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Carbon-yl{3,3'-di-tert-butyl-5,5'-dimeth-oxy-2,2'-bis-[(4,4,5,5-tetra-methyl-1,3,2-dioxaphospho-lan-2-yl)-oxy]biphenyl-κ(2) P,P'}hydrido(triphenyl-phosphane-κP)rhodium(I) diethyl ether tris-olvate.

作者信息

Selent Detlef, Spannenberg Anke, Börner Armin

机构信息

Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):m14. doi: 10.1107/S1600536812049124. Epub 2012 Dec 5.

DOI:10.1107/S1600536812049124
PMID:23476316
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3588287/
Abstract

In the title compound, [RhH(C74H68O8P2)(C18H15P)(CO)]·3C4H10O, the CHP3 coordination set at the Rh(I) ion is arranged in a distorted trigonal-bipyramidal geometry with the P atoms adopting equatorial coordination sites and the C atom of the carbonyl ligand as well as the H atom adopting the axial sites. The asymmetric unit contains two very similar mol-ecules of the rhodium complex, two half-occupied diethyl ether mol-ecules and further diethyl ether solvent mol-ecules which could not be modelled successfully. Therefore contributions of the latter were removed from the diffraction data using the SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155].

摘要

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引用本文的文献

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本文引用的文献

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2
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
3
A short history of SHELX.
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Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.