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4-氟-2-[(3-甲基-苯基)亚氨基甲基]苯酚

4-Fluoro-2-[(3-methyl-phen-yl)imino-meth-yl]phenol.

作者信息

Brink Alice, Visser Hendrik G, Roodt Andreas

机构信息

Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein 9300, South Africa.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):o1071. doi: 10.1107/S1600536812010513. Epub 2012 Mar 14.

DOI:10.1107/S1600536812010513
PMID:22589937
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3344028/
Abstract

The title compound, C(14)H(12)FNO, crystallizes as the trans phenol-imine tautomer. The two benzene rings are essentially coplanar, being inclined to one another by 9.28 (7)°. This is at least in part due to the intra-molecular O-H⋯N hydrogen bond between the hy-droxy O atom and the imine N atom. The crystal structure is stabilized by an array of weak C-H⋯O and C-H⋯F inter-actions, which link the mol-ecules into a stable three-dimensional network.

摘要

标题化合物C(14)H(12)FNO以反式酚亚胺互变异构体形式结晶。两个苯环基本共面，彼此间夹角为9.28 (7)°。这至少部分归因于羟基O原子与亚胺N原子之间的分子内O-H⋯N氢键。晶体结构通过一系列弱的C-H⋯O和C-H⋯F相互作用得以稳定，这些相互作用将分子连接成一个稳定的三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/abb9/3344028/d6c0c91507c5/e-68-o1071-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/abb9/3344028/92f3a1c64ac1/e-68-o1071-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/abb9/3344028/f820c105d9e9/e-68-o1071-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/abb9/3344028/77c68aa137f8/e-68-o1071-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/abb9/3344028/d6c0c91507c5/e-68-o1071-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/abb9/3344028/92f3a1c64ac1/e-68-o1071-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/abb9/3344028/f820c105d9e9/e-68-o1071-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/abb9/3344028/77c68aa137f8/e-68-o1071-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/abb9/3344028/d6c0c91507c5/e-68-o1071-fig4.jpg

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