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高氯酸氯代[N,N'-二苄基-N,N'-双-(吡啶-2-基甲基)乙烷-1,2-二胺]合铜(II)甲醇单溶剂合物

Chlorido[N,N'-dibenzyl-N,N'-bis-(pyridin-2-ylmeth-yl)ethane-1,2-diamine]-copper(II) perchlorate methanol monosolvate.

作者信息

Song Hui-Ting, Mao Jia-Wei, Liu Ming, Pan Zhi-Quan

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):m694-5. doi: 10.1107/S1600536812017941. Epub 2012 Apr 28.

DOI:10.1107/S1600536812017941
PMID:22590174
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3344412/
Abstract

In the title solvated mol-ecular salt, [CuCl(C(28)H(30)N(4))]ClO(4)·CH(3)OH, the Cu(2+) ion is coordinated by the N,N',N'',N'''-tetra-dentate ligand and a chloride ion, generating a very distorted square-based pyramidal CuN(4)Cl coordination geometry with the Cl(-) ion in the basal position. In the crystal, the solvent mol-ecules and anions are linked by weak O-H⋯O hydrogen bonding.

摘要

在标题化合物溶剂化分子盐[CuCl(C₂₈H₃₀N₄)]ClO₄·CH₃OH中，Cu²⁺离子由N,N',N'',N'''-四齿配体和一个氯离子配位，形成一个非常扭曲的四方锥型CuN₄Cl配位几何结构，其中Cl⁻离子位于基底位置。在晶体中，溶剂分子和阴离子通过弱的O—H⋯O氢键相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/641b/3344412/a7250215036e/e-68-0m694-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/641b/3344412/a7250215036e/e-68-0m694-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/641b/3344412/a7250215036e/e-68-0m694-fig1.jpg

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