Du Jing-Ru, Li Kui-Xiao, Zhou Jun, Gan Yi-Ping, Huang Guo-Zhong
Civil & Environment Engineering School, University of Science and Technology Beijing, Beijing 100083, China.
Huan Jing Ke Xue. 2011 Aug;32(8):2292-7.
Sodium hypochlorite (NaClO) used in wastewater disinfection was assessed by examining its performances in lab fed by the effluent from a MBR treatment plant. The influence of sodium hypochlorite initial concentrations (0.5-3.0 mg/L) on the presence of indicator microorganisms (total coliforms, fecal coliforms), disinfection by-products (DBPs) concentrations and the acute toxicity were evaluated. Results indicate the total coliforms and the fecal coliform were 1500-2400 and 10-40 CFU/L, which is difficult to meet the present reclaimed water quality standards. A chlorine dose of 2.0 mg/L and contact for 1 h could achieve a 3 lg indicator bacteria reduction in MBR effluent samples. THMs (trihalomethanes) analysis indicated that concentrations of THMs increase with the raise of the active chlorine dose. After adding sodium hypochlorite 1 h the concentrations of trihalomethanes (THMs) were 16.22, 7.35 microg/L respectively and chloroform (TCM) accounted for 87% of THMs, the haloacetic acids (HAAs) was involved trichloroacetic acid (TCAA) 2.01 microg/L, dichloroacetic acid (DCAA) 1.58 microg/L and under the national limits. Luminescence bacteria acute toxicity analysis showed that the chlorinated effluent has higher inhibition rate (48%) in comparison to the control with a chlorine dosage of 3.0 mg/L. The results which could provide theoretical basis to production show that NaClO disinfection not only can inactivate microbe with the DBPs and acute toxicity of the effluent under the safety limits, but also meet the requirement of health and safety.
通过在实验室中以膜生物反应器(MBR)处理厂的出水为进水,评估了用于废水消毒的次氯酸钠(NaClO)的性能。评估了次氯酸钠初始浓度(0.5 - 3.0 mg/L)对指示微生物(总大肠菌群、粪大肠菌群)的存在、消毒副产物(DBPs)浓度以及急性毒性的影响。结果表明,总大肠菌群和粪大肠菌群分别为1500 - 2400 CFU/L和10 - 40 CFU/L,难以达到目前的再生水水质标准。在MBR出水样品中,投加2.0 mg/L的氯并接触1小时可实现指示细菌减少3个对数级。三卤甲烷(THMs)分析表明,THMs的浓度随着有效氯剂量的增加而升高。添加次氯酸钠1小时后,三卤甲烷(THMs)的浓度分别为16.22、7.35 μg/L,氯仿(TCM)占THMs的87%,卤乙酸(HAAs)涉及三氯乙酸(TCAA)2.01 μg/L、二氯乙酸(DCAA)1.58 μg/L,均在国家限值以下。发光细菌急性毒性分析表明,与投加3.0 mg/L氯的对照相比,氯化后的出水具有更高的抑制率(48%)。该结果可为生产提供理论依据,表明NaClO消毒不仅能使微生物失活,且出水的消毒副产物和急性毒性在安全限值以下,还能满足健康和安全要求。