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在介质阻挡放电中对二氯苯的分解。

Decomposition of dichlorobenzene in a dielectric barrier discharge.

机构信息

Department of Chemical Engineering, Institut Teknologi Bandung, Labtek X, Kampus ITB, Jalan Ganesha 10, Bandung, 40132, Indonesia.

出版信息

Environ Technol. 2012 Feb-Mar;33(4-6):663-6. doi: 10.1080/09593330.2011.587026.

Abstract

This paper presents a decomposition study of 1,2-dichlorobenzene (DCB) using a dielectric barrier discharge (DBD). The discussion is focused on the effects of variations of carrier gases, DCB concentrations and input voltages on the decomposition performance. The DCB conversion was conducted inside a cylindrical reactor consists of silver film as the outside electrode and a spring coil as the inside electrode. Two carrier gases, i.e. air and nitrogen, were introduced to the reactor at a total flow rate of 500 mL/min with DCB concentrations of 100, 300 and 500 ppm. Gaseous products, before and after plasma treatment, were analysed by a gas chromatography and FT-IR spectroscopy, and the consumed power was calculated from Lissajous' figure analysis. In order to improve the decomposition performance, various TiO2-supported catalysts were employed.

摘要

本文利用介质阻挡放电(DBD)对 1,2-二氯苯(DCB)进行了分解研究。讨论集中在载气、DCB 浓度和输入电压变化对分解性能的影响。DCB 转化在内径为 50mm 的圆柱形反应器中进行,反应器的外电极为银膜,内电极为螺旋形弹簧。两种载气,即空气和氮气,以 500mL/min 的总流速被引入到反应器中,同时 DCB 的浓度分别为 100、300 和 500ppm。在等离子体处理前后,通过气相色谱和傅里叶变换红外光谱法对气态产物进行了分析,并从李萨如图形分析中计算出所消耗的功率。为了提高分解性能,采用了各种负载型 TiO2 催化剂。

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