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非热等离子体反应器中雾态苯酚的降解。

Degradation of phenol in mists by a non-thermal plasma reactor.

机构信息

School of Chemistry and Environment, Beihang University, Beijing 100191, China.

出版信息

Chemosphere. 2011 Aug;84(9):1296-300. doi: 10.1016/j.chemosphere.2011.05.007. Epub 2011 May 31.

Abstract

A link tooth wheel-cylinder non-thermal plasma reactor was set up to investigate the degradation of phenol in the mists. In addition, the decomposition efficiency of phenol, TOC removal, and byproduct formation were investigated. The stable discharge was achieved in both air and the mist condition. The decomposition efficiency and TOC removal increased with increasing the input power. For the input power of 3.6 W, the phenol decomposition and TOC removal reached 90% and 47%, respectively. Phenol degradation byproducts were identified as small molecular organic acids, including formic acid, acetic acid, and oxalic acid. Their masses in the trapped solutions first increased and then decreased slightly with increasing the input power. Therefore, the biodegradation capacity of the phenol degradation byproducts can be improved.

摘要

建立了链接齿轮-圆柱非热等离子体反应器,以研究雾相中苯酚的降解。此外,还研究了苯酚的分解效率、TOC 去除率和副产物的形成。在空气和雾两种条件下均实现了稳定放电。随着输入功率的增加,分解效率和 TOC 去除率均增加。输入功率为 3.6 W 时,苯酚分解和 TOC 去除率分别达到 90%和 47%。鉴定出的苯酚降解副产物为小分子有机酸,包括甲酸、乙酸和草酸。随着输入功率的增加,它们在捕获溶液中的质量先增加后略有减少。因此,可以提高苯酚降解副产物的生物降解能力。

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