Technische Universität Berlin, Department of Chemistry, Cluster of Excellence Unifying Concepts in Catalysis, Strasse des 17. Juni 115, 10623 Berlin, Germany.
ChemSusChem. 2012 Jul;5(7):1195-8. doi: 10.1002/cssc.201200125. Epub 2012 May 25.
Iron will: The iron-catalyzed depolymerization of a range of polyethers is studied. The products of the depolymerization reactions are chloroesters, which can be used as starting materials for new polymers. In the presence of simple iron salts extraordinary catalyst activities and selectivities are feasible at low temperature.
研究了一系列聚醚的铁催化解聚。解聚反应的产物是氯酯，可作为新型聚合物的起始原料。在简单的铁盐存在下，在低温下即可实现非凡的催化剂活性和选择性。
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