Liguori Francesca, Moreno-Marrodán Carmen, Barbaro Pierluigi
Consiglio Nazionale delle Ricerche, Istituto di Chimica dei Composti Organo Metallici, Via Madonna del Piano 10, 50019 Sesto Fiorentino, Firenze, Italy.
Beilstein J Org Chem. 2021 Mar 2;17:589-621. doi: 10.3762/bjoc.17.53. eCollection 2021.
Metal-catalysed depolymerisation of plastics to reusable building blocks, including monomers, oligomers or added-value chemicals, is an attractive tool for the recycling and valorisation of these materials. The present manuscript shortly reviews the most significant contributions that appeared in the field within the period January 2010-January 2020 describing selective depolymerisation methods of plastics. Achievements are broken down according to the plastic material, namely polyolefins, polyesters, polycarbonates and polyamides. The focus is on recent advancements targeting sustainable and environmentally friendly processes. Biocatalytic or unselective processes, acid-base treatments as well as the production of fuels are not discussed, nor are the methods for the further upgrade of the depolymerisation products.
金属催化的塑料解聚为可重复使用的结构单元,包括单体、低聚物或高附加值化学品,是这些材料回收和增值的一种有吸引力的工具。本手稿简要回顾了2010年1月至2020年1月期间该领域出现的关于塑料选择性解聚方法的最重要贡献。成果根据塑料材料进行分类,即聚烯烃、聚酯、聚碳酸酯和聚酰胺。重点是针对可持续和环境友好工艺的最新进展。生物催化或非选择性工艺、酸碱处理以及燃料生产均未讨论,解聚产物的进一步升级方法也未讨论。