基于[6]轮烷的[2]索烃的热响应穿梭行为。
Thermally responsive shuttling behavior of a pillar[6]arene-based [2]rotaxane.
机构信息
Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan.
出版信息
Chem Commun (Camb). 2012 Jul 11;48(54):6842-4. doi: 10.1039/c2cc32865h. Epub 2012 May 31.
PMID:22648293
Abstract
A [2]rotaxane constructed from a per-ethylated pillar[6]arene as a wheel and a pyridinium derivative as an axle was prepared. The wheel segment of the per-ethylated pillar[6]arene moved from one station to another along the axle as a result of thermal stimuli.
摘要
一种[2]轮烷是由一个全乙基化的[6]柱芳烃作为轮和一个吡啶鎓衍生物作为轴制备的。由于热刺激，全乙基化[6]柱芳烃的轮段沿着轴从一个位置移动到另一个位置。
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