二价锌对 2-取代噻吩的配位：构建具有[16]冠-4 锌环核的笼状结构。
Dizincation of a 2-substituted thiophene: constructing a cage with a [16]crown-4 zincocyclic core.
机构信息
WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK.
出版信息
Angew Chem Int Ed Engl. 2012 Jul 9;51(28):6934-7. doi: 10.1002/anie.201203344. Epub 2012 Jun 8.
PMID:22685018
Abstract
Metal detector: a bowl-shaped nanomolecule (see picture; S yellow, C gray, Zn blue) containing an unprecedented 16-atom ZnC(3) "anti-crown" ring has been unearthed by isolating a dizincated 2-substituted thiophene intermediate that would normally be hidden in tandem functionalization methodology.
摘要
金属探测器
一个碗状纳米分子（见图；S 黄色，C 灰色，Zn 蓝色），其中包含一个前所未有的 16 原子 ZnC(3)“反冠”环，通过分离通常会隐藏在串联功能化方法中的二锌化 2-取代噻吩中间体而被发现。
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