钯催化的芳基硼酸对氯三氟乙烯的芳基化反应。
Pd-catalyzed arylation of chlorotrifluoroethylene using arylboronic acids.
机构信息
Catalysis Group, Sagami Chemical Research Institute, 2743-1 Hayakawa, Ayase, Kanagawa 252-1193, Japan.
出版信息
Org Lett. 2012 Jul 6;14(13):3454-7. doi: 10.1021/ol3014107. Epub 2012 Jun 12.
PMID:22691065
Abstract
The palladium-catalyzed cross-coupling of chlorotrifluoroethylene and arylboronic acids proceeds in the presence of a base and H(2)O to provide α,β,β-trifluorostyrene derivatives in satisfactory yields.
摘要
钯催化的氯三氟乙烯和芳基硼酸的交叉偶联反应在碱和 H(2)O 的存在下进行，以令人满意的收率得到α,β,β-三氟苯乙烯衍生物。
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