阳离子钯（II）/联吡啶催化芳基硼酸与芳醛的加成反应。不对称三芳基甲烷的一锅法合成。
Cationic Pd(II)/bipyridine-catalyzed addition of arylboronic acids to arylaldehydes. One-pot synthesis of unsymmetrical triarylmethanes.
作者信息
Lin Shaohui, Lu Xiyan
机构信息
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China.
出版信息
J Org Chem. 2007 Dec 7;72(25):9757-60. doi: 10.1021/jo071232k. Epub 2007 Nov 14.
PMID:17999518
Abstract
Cationic Pd(II) complex-catalyzed addition of arylboronic acids to aldehydes with low catalyst loading was developed with high yields. One-pot synthesis of unsymmetrical triarylmethanes from arylboronic acids, aryl aldehydes, and electron-rich arenes was achieved in high yields.
摘要
开发了一种阳离子钯（II）配合物催化的芳基硼酸与醛的加成反应，该反应在低催化剂负载量下具有高产率。实现了从芳基硼酸、芳基醛和富电子芳烃一锅法高产率合成不对称三芳基甲烷。
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