Dept. of Chemistry, Aarhus University, Langelandsgade 140, DK-8000 Aarhus C, Denmark.
Chem Commun (Camb). 2012 Jul 21;48(57):7203-5. doi: 10.1039/c2cc32711b. Epub 2012 Jun 12.
An efficient electromediated aerobic ipso-hydroxylation reaction of aryl and alkyl boronic acids has been developed. Furthermore, mechanistic insight into the role of superoxide anions in this reaction has also been provided based on electrochemical studies and experimental results.
发展了一种高效的电介导有氧芳基和烷基硼酸的反位羟基化反应。此外,基于电化学研究和实验结果,还提供了超氧阴离子在该反应中作用的机理见解。