Food Safety and Analytical Quality Control Laboratory, Central Food Technological Research Institute, Mysore 570020, India.
J Sci Food Agric. 2012 Aug 30;92(11):2227-33. doi: 10.1002/jsfa.5638. Epub 2012 Jun 12.
The nature of the container material and temperature employed for deep-frying can have an influence on the development of trans fatty acids (TFAs) in the fat used. The present study was undertaken to determine the effect of heating vegetable oils and partially hydrogenated vegetable fats with different initial TFA content in stainless steel, Hindalium (an aluminium alloy), cast iron and glass containers. Ground nut oil (oil 1), refined, bleached and deodorised (RBD) palmolein (oil 2) and two partially hydrogenated vegetable oils with low (fat 1) and high (fat 2) TFA content were uniformly heated at 175-185 °C over a period of 12 h.
An increase in TFA content to 20 g kg⁻¹ was observed in oil 2 in the cast iron container, while a decrease in TFA content of 20-30 g kg⁻¹ was observed in fat 2 in all containers. The heating process of fats and oils also led to an increase in Butyro refractometer reading and colour values.
This study showed that the TFA 18:1t content of oil 1, oil 2 and fat 1 increased with repeated or prolonged heating. The cast iron container showed the highest increase in TFA 18:1t for RBD palmolein (oil 2). The amount of linoleic acid trans isomers formed in the heating process was negligible. Fat 2 with high initial TFA content showed a decrease in TFA 18:1 and 18:2 on heating in all containers. Oils heated in glass and stainless steel containers showed less TFA 18:1t formation.
油炸时容器材料的性质和所使用的温度会影响脂肪中反式脂肪酸(TFAs)的形成。本研究旨在确定在不锈钢、Hindalium(铝合金)、铸铁和玻璃容器中加热不同初始 TFA 含量的植物油和部分氢化植物油时,容器材料的性质和所使用的温度对 TFA 形成的影响。将花生油(油 1)、精炼、漂白和除臭(RBD)棕榈油(油 2)以及两种 TFA 含量较低(脂肪 1)和较高(脂肪 2)的部分氢化植物油在 175-185°C 下均匀加热 12 小时。
在铸铁容器中,油 2 的 TFA 含量增加到 20 g kg⁻¹,而在所有容器中,脂肪 2 的 TFA 含量减少了 20-30 g kg⁻¹。油脂的加热过程还导致了布氏折射计读数和颜色值的增加。
本研究表明,油 1、油 2 和脂肪 1 的 18:1t TFA 含量随着反复或长时间加热而增加。对于 RBD 棕榈油(油 2),铸铁容器显示出最高的 18:1t TFA 增加量。在加热过程中形成的亚油酸反式异构体数量可以忽略不计。在所有容器中加热时,高初始 TFA 含量的脂肪 2 显示出 TFA 18:1 和 18:2 的减少。在玻璃和不锈钢容器中加热的油显示出较少的 TFA 18:1t 形成。