环金属化金(III)氢氧化物作为多功能合成子用于 Au-N、Au-C 配合物和发光化合物。
Cyclometallated gold(III) hydroxides as versatile synthons for Au-N, Au-C complexes and luminescent compounds.
机构信息
Wolfson Materials and Catalysis Centre, School of Chemistry, University of East Anglia, Norwich, NR4 7TJ, UK.
出版信息
Chem Commun (Camb). 2012 Jul 25;48(58):7247-9. doi: 10.1039/c2cc33104g. Epub 2012 Jun 13.
PMID:22695754
Abstract
The gold(III) hydroxide κ(3)-(C^N^C)Au(OH) reacts with C-H and N-H compounds and arylboronic acids to produce a range of perfluoroaryls, N-heterocyclic and alkynyl compounds in high yields; some of which show unexpectedly strong modulation of their photoluminescence from yellow to blue [(C^N^C) = 2,6-(C(6)H(3)Bu(t))(2)pyridine].
摘要
三价金(III)氢氧化物κ(3)-(C^N^C)Au(OH) 可与 C-H 和 N-H 化合物以及芳基硼酸反应，高产率地生成一系列全氟芳基、N-杂环和炔基化合物；其中一些化合物的光致发光性质出人意料地从黄色调蓝 [(C^N^C) = 2,6-(C(6)H(3)Bu(t))(2)pyridine] 得到了很好的调控。
Zotero 插件