Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, United States.
Chem Rev. 2021 Jul 28;121(14):8979-9038. doi: 10.1021/acs.chemrev.0c00774. Epub 2021 Feb 16.
Homogeneous gold catalysis has experienced extraordinary development since the dawn of this millennium. Oxidative gold catalysis is a vibrant and fertile subfield and has over the years delivered a diverse array of versatile synthetic methods of exceptional value to synthetic practices. This review aims to cover this topic in a comprehensive manner. The discussions are organized by the mechanistic aspects of the metal oxidation states and further by the types of oxidants or oxidizing functional groups. Synthetic applications of oxidative gold catalysis are also discussed.
自本世纪初以来,均相金催化经历了非凡的发展。氧化金催化是一个充满活力和富有成效的分支领域,多年来为合成实践提供了多种具有特殊价值的多功能合成方法。本综述旨在全面涵盖这一主题。讨论按金属氧化态的机理方面以及氧化剂或氧化官能团的类型进行组织。还讨论了氧化金催化的合成应用。