Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany.
Angew Chem Int Ed Engl. 2012 Jul 16;51(29):7314-7. doi: 10.1002/anie.201202853. Epub 2012 Jun 13.
Diastereomers made to order: In an unprecedented ligand-controlled process a racemic mixture of four stereoisomers can be converted with high selectivity into each one of the diastereomers of the product, at will (see scheme). The mechanism of this deracemization of epimers, that is, a de-epimerization, was also studied.
在前所未有的配体控制反应中，通过高选择性地将外消旋混合物的四种立体异构体转化为产物的每个非对映异构体（见方案）。还研究了这种外消旋化的差向异构体，即去外消旋化的机制。
