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周期性变几何管状结构中的力依赖移动性和熵整流。

Force-dependent mobility and entropic rectification in tubes of periodically varying geometry.

机构信息

Departamento de Fisica, Universidad Autonoma Metropolitana-Iztapalapa, Mexico, 09340 Distrito Federal, Mexico.

出版信息

J Chem Phys. 2012 Jun 7;136(21):214110. doi: 10.1063/1.4726193.

DOI:10.1063/1.4726193
PMID:22697533
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3382925/
Abstract

We investigate transport of point Brownian particles in a tube formed by identical periodic compartments of varying diameter, focusing on the effects due to the compartment asymmetry. The paper contains two parts. First, we study the force-dependent mobility of the particle. The mobility is a symmetric non-monotonic function of the driving force, F, when the compartment is symmetric. Compartment asymmetry gives rise to an asymmetric force-dependent mobility, which remains non-monotonic when the compartment asymmetry is not too high. The F-dependence of the mobility becomes monotonic in tubes formed by highly asymmetric compartments. The transition of the F-dependence of the mobility from non-monotonic to monotonic behavior results in important consequences for the particle motion under the action of a time-periodic force with zero mean, which are discussed in the second part of the paper: In a tube formed by moderately asymmetric compartments, the particle under the action of such a force moves with an effective drift velocity that vanishes at small and large values of the force amplitude having a maximum in between. In a tube formed by highly asymmetric compartments, the effective drift velocity monotonically increases with the amplitude of the driving force and becomes unboundedly large as the amplitude tends to infinity.

摘要

我们研究了点布朗粒子在由不同直径的相同周期性隔室组成的管中的输运,重点研究了隔室不对称引起的影响。本文包含两部分。首先,我们研究了粒子的力相关迁移率。当隔室对称时,迁移率是驱动力 F 的对称非单调函数。隔室不对称会导致不对称的力相关迁移率,当隔室不对称不太高时,它仍然是非单调的。当由高度不对称的隔室形成的管时,迁移率对 F 的依赖性变为单调。迁移率对 F 的依赖性从非单调到单调行为的转变对在具有零均值的时变周期性力作用下的粒子运动产生了重要的后果,这在本文的第二部分进行了讨论:在由中等不对称隔室形成的管中,在这种力的作用下,粒子以有效漂移速度运动,该速度在力幅度较小时和较大时为零,在中间有最大值。在由高度不对称隔室形成的管中,有效漂移速度随驱动力幅度单调增加,并随着幅度趋于无穷大而变得无界大。

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本文引用的文献

1
Driven Brownian transport through arrays of symmetric obstacles.通过对称障碍物阵列的驱动布朗输运。
Phys Rev E Stat Nonlin Soft Matter Phys. 2012 Jan;85(1 Pt 1):011101. doi: 10.1103/PhysRevE.85.011101. Epub 2012 Jan 3.
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Cooperative rectification in confined Brownian ratchets.受限布朗棘轮中的协同整流
Phys Rev E Stat Nonlin Soft Matter Phys. 2012 Jan;85(1 Pt 1):010105. doi: 10.1103/PhysRevE.85.010105. Epub 2012 Jan 20.
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Entropic splitter for particle separation.用于粒子分离的熵分离器。
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Communication: drift velocity of Brownian particle in a periodically tapered tube induced by a time-periodic force with zero mean: dependence on the force period.通讯:零均值时变周期力作用下布朗粒子在周期性渐缩管中的扩散速度:对力周期的依赖性。
J Chem Phys. 2011 Sep 28;135(12):121102. doi: 10.1063/1.3647873.
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Driven diffusion in a periodically compartmentalized tube: homogeneity versus intermittency of particle motion.周期性分隔管中的驱动扩散:粒子运动的均匀性与间歇性。
J Phys Chem B. 2011 Apr 14;115(14):3992-4002. doi: 10.1021/jp112393q. Epub 2011 Mar 18.
6
Communication: Turnover behavior of effective mobility in a tube with periodic entropy potential.交流:管中有效迁移率的周转率行为与周期熵势。
J Chem Phys. 2011 Mar 14;134(10):101102. doi: 10.1063/1.3561680.
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Communications: Drift and diffusion in a tube of periodically varying diameter. Driving force induced intermittency.通讯:变径管中的扩散和漂移。驱动力引起的间歇性。
J Chem Phys. 2010 Jun 14;132(22):221104. doi: 10.1063/1.3451115.
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Variance of residence time spent by diffusing particle in a sub-domain. Path integral based approach.扩散粒子在子域中停留时间的方差。基于路径积分的方法。
Chem Phys. 2010 May 1;370(1-3):253-257. doi: 10.1016/j.chemphys.2009.10.020.
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Mobility in periodic channels formed by cylindrical cavities.由圆柱形空洞形成的周期性通道中的迁移率。
J Chem Phys. 2010 Apr 28;132(16):166101. doi: 10.1063/1.3402779.
10
Rectification currents in two-dimensional artificial channels.二维人工通道中的整流电流。
Phys Rev E Stat Nonlin Soft Matter Phys. 2009 Jul;80(1 Pt 1):011120. doi: 10.1103/PhysRevE.80.011120. Epub 2009 Jul 17.