Carbon Nanomaterials Design Laboratory, Research Institute of Advanced Materials, Seoul National University, Republic of Korea.
Adv Mater. 2012 Aug 2;24(29):4010-3. doi: 10.1002/adma.201200790. Epub 2012 Jun 15.
A straightforward method for significantly improving the moisture resistance of MOFs is described. In the proposed method, MOFs are subjected to thermal treatment, thus inducing the formation of an amorphous carbon coating on the MOF surfaces that prevents hydrolysis. This approach should open up new practical applications for MOFs in areas hitherto unexplored due to concerns regarding moisture sensitivity.
本文描述了一种显著提高 MOFs 耐湿性的简便方法。该方法通过对 MOFs 进行热处理,在 MOF 表面诱导形成无定形碳涂层,从而防止水解。由于对湿度敏感的问题,这种方法应该为 MOFs 在以前未探索过的领域开辟新的实际应用。