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一座前原地回收铀矿地下水中污染物水平及修复效果的测定

Determination of contaminant levels and remediation efficacy in groundwater at a former in situ recovery uranium mine.

作者信息

Borch Thomas, Roche Nicholas, Johnson Thomas E

机构信息

Department of Soil and Crop Sciences, Colorado State University, Fort Collins, Colorado 80523-1170, USA.

出版信息

J Environ Monit. 2012 Jul;14(7):1814-23. doi: 10.1039/c2em30077j. Epub 2012 Jun 15.

Abstract

There has been increasing interest in uranium mining in the United States via in situ recovery techniques. One of the main environmental concerns with in situ uranium mining is the potential for spreading groundwater contamination. There is a dearth of detailed analysis and information regarding the outcome of in situ uranium mine remediation to ascertain the environmental impacts. Regulatory measurements performed at a Wyoming in situ uranium mine were collected and analysed to ascertain the efficacy of remediation and potential long term environmental impact. Based on the measurements, groundwater sweeping followed by reverse osmosis (RO) treatment proved to be a highly efficient method of remediation. However, injection of a reductant in the form of H(2)S after groundwater sweeping and RO did not further reduce the aqueous concentration of U, Mn, or Fe. Low concentrations of target species at monitoring wells outside the mined area appear to indicate that in the long term, natural attenuation is likely to play a major role at reductively immobilizing residual (after remediation) concentrations of U(VI) thus preventing it from moving outside the mined area. Our analysis indicates the need for additional monitoring wells and sampling in conjunction with long term monitoring to better understand the impacts of the different remediation techniques.

摘要

美国通过原地回收技术进行铀矿开采的兴趣与日俱增。原地铀矿开采的主要环境问题之一是存在地下水污染扩散的可能性。关于原地铀矿修复结果以确定其环境影响的详细分析和信息匮乏。收集并分析了在怀俄明州一个原地铀矿进行的监管测量数据,以确定修复效果和潜在的长期环境影响。基于这些测量结果,先进行地下水吹扫然后采用反渗透(RO)处理被证明是一种高效的修复方法。然而,在地下水吹扫和RO处理之后注入以H₂S形式存在的还原剂并没有进一步降低水中U、Mn或Fe的浓度。矿区外监测井中目标物种的低浓度似乎表明,从长期来看,自然衰减可能在还原固定(修复后)U(VI)的残留浓度从而防止其迁移到矿区外方面发挥主要作用。我们的分析表明,需要增设监测井并结合长期监测进行采样,以更好地了解不同修复技术的影响。

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