[10]环并苯的选择性合成与晶体结构。
Selective synthesis and crystal structure of [10]cycloparaphenylene.
机构信息
Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.
出版信息
Org Lett. 2012 Jul 6;14(13):3284-7. doi: 10.1021/ol301242t. Epub 2012 Jun 18.
PMID:22708699
Abstract
[10]Cycloparaphenylene ([10]CPP) was selectively synthesized in four steps in 13% overall yield from commercially available 4,4'-diiodobiphenyl by using mono-I-Sn exchange, Sn-Pt transmetalation, I-Pd exchange, and subsequent oxidative coupling reactions. The single-crystal X-ray structure of [10]CPP is described.
摘要
[10]环对苯撑（[10]CPP）由商业可得的 4,4'-二碘联苯经单-I-Sn 交换、Sn-Pt 反金属化、I-Pd 交换和随后的氧化偶联反应，以 13%的总收率选择性地在四步反应中合成。描述了[10]CPP 的单晶 X 射线结构。
Zotero 插件