由笼型 Mo3S4 簇催化剂介导的对硝基芳烃的化学选择性转移氢化。
Chemoselective transfer hydrogenation to nitroarenes mediated by cubane-type Mo3S4 cluster catalysts.
机构信息
Departament de Química Física i Analítica, Universitat Jaume I, Av. Sos Baynat s/n, 12071 Castelló de la Plana, Spain.
出版信息
Angew Chem Int Ed Engl. 2012 Jul 27;51(31):7794-8. doi: 10.1002/anie.201202584. Epub 2012 Jun 18.
PMID:22711684
Abstract
Chemoselective cubes: Cubane-type Mo(3)S(4)X(3)(dmpe)(3) clusters (dmpe = 1,2-(bis)dimethylphosphinoethane), in combination with an azeotropic 5:2 mixture of HCOOH and NEt(3) as the reducing agent, act as selective cluster catalysts (X = H) or precatalysts (X = Cl) for the transfer hydrogenation of functionalized nitroarenes, without the formation of hazardous hydroxylamines.
摘要
选择性立方烷
立方烷型 [Mo(3)S(4)X(3)(dmpe)(3)]⁺簇（dmpe = 1,2-（双）二甲基膦乙烷），与等摩尔比的 HCOOH 和 NEt(3) 的共沸混合物（5:2）作为还原剂，可作为功能化硝基芳烃转移氢化的选择性簇催化剂（X = H）或前催化剂（X = Cl），而不会形成危险的羟胺。
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