三（3-氯-戊烷-2,4-二酮-O,O'双齿配位）铝
Tris(3-chloro-pentane-2,4-dionato-κ(2)O,O')aluminium.
作者信息
Perdih Franc
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):m806. doi: 10.1107/S1600536812023203. Epub 2012 May 26.
Abstract
In the title compound, [Al(C(5)H(6)ClO(2))(3)], the Al(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro-pentane-2,4-dionate ligands in an octa-hedral environment. Al-O bond lengths are in the range 1.8741 (14)-1.8772 (14) Å. In the crystal, mol-ecules are linked via C-H⋯Cl contacts.
摘要
在标题化合物[Al(C₅H₆ClO₂)₃]中，Al(III)阳离子位于二重旋转轴上，在八面体环境中由来自三个3-氯戊烷-2,4-二酮配体的六个O原子配位。Al - O键长在1.8741 (14) - 1.8772 (14) Å范围内。在晶体中，分子通过C - H⋯Cl接触相连。
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