双（2,4-戊二酮-κO,O'）（1,10-菲咯啉-κN,N'）钴（II）
Bis(pentane-2,4-dionato-κO,O')(1,10-phenanthroline-κN,N')cobalt(II).
作者信息
Perdih Franc
机构信息
Faculty of Chemistry and Chemical Technology, University of Ljubljana, Aškerčeva 5, PO Box 537, SI-1000 Ljubljana, Slovenia, and CO EN-FIST, Dunajska 156, SI-1000 Ljubljana, Slovenia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1697. doi: 10.1107/S1600536811046216. Epub 2011 Nov 5.
In the title compound, [Co(C(5)H(7)O(2))(2)(C(12)H(8)N(2))], the Co(II) cation lies on a twofold rotation axis and is coordinated by four O atoms from two acetyl-acetonate (acac) ligands and two N atoms from a 1,10-phenanthroline (phen) ligand in a slightly distorted octa-hedral environment, with Co-O bond lengths of 2.0565 (11) and 2.0641 (11) Å and Co-N bond lengths of 2.1630 (12) Å. In the crystal, there are no significant hydrogen-bonding or π-π inter-actions.
在标题化合物[Co(C₅H₇O₂)₂(C₁₂H₈N₂)]中，Co(II)阳离子位于一个二重旋转轴上，在略微扭曲的八面体环境中，由来自两个乙酰丙酮（acac）配体的四个O原子和来自一个1,10-菲咯啉（phen）配体的两个N原子配位，Co - O键长为2.0565 (11) Å和2.0641 (11) Å，Co - N键长为2.1630 (12) Å。在晶体中，不存在显著的氢键或π - π相互作用。
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