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[三门峡水库河滨湿地沉积物重金属分布及风险评估]

[Heavy metals distribution and risk assessment of sediments in the riverine wetland of Sanmenxia Reservoir].

作者信息

Ao Liang, Shan Bao-Qing, Zhang Hong, Tang Wen-Zhong

机构信息

State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China.

出版信息

Huan Jing Ke Xue. 2012 Apr;33(4):1176-81.

Abstract

The survey for contents and fractions of heavy metal in sediments of riverine wetland in Sanmenxia Reservoir were carried out. Sediment pollution index was applied to assess the potential ecological risk and mass fraction of heavy metal in surface sediment was conducted for release risk assessment. The results showed that the total concentrations of Cr, Ni, Cu, Zn, Cd and Pb ranged in 25.8-68.5, 12.1-36.7, 3.25-48.74, 33.5-472.4, 0.16-0.69 and 9.04-90.74 mg x kg(-1), respectively. The heavy metal contents in the sediments increased obviously from the upper reaches of reservoir to Sanmenxia dam. The concentrations of Ni, Cu, Zn, Cd, Pb in sediments were higher in lower reach located after Weihe River than those of the upstream. The Weihe River was the biggest branch of Yellow River, and heavy metals accumulated obviously in the sediments of typical polluted branch (Hongnongjian River) , which might be attributed to the long-term discharge of industrial wastewater. The sediment pollution index (SPI) of Sanmenxia Reservoir ranged from 1.83 to 7.39, with an average value for 3.11. Sediment pollution aggravated in the downstream after Weihe River flowed in, and SPI reached 6.33 in Hongnongjian River mouth for medium risk. The exchangeable and carbonates fraction of Cd, Cu and Pb mass fractions in surface sediments accounted for 63.8%-85.7%, 6.58%-22.62% and 10.6%-28.9%, respectively. The pollutants discharge in branches caused heavy metal accumulation, ecological risk aggravation in lower reach of Sanmenxia basin. And the release risk followed the sequence Cd > Pb > Cu > Ni in surface sediment. The conclusions of this article supplied reference and basis for sediment pollution treatment and in situ remediation.

摘要

对三门峡水库河滨湿地沉积物中重金属的含量及形态进行了调查。应用沉积物污染指数评估潜在生态风险,并对表层沉积物中重金属的质量分数进行释放风险评估。结果表明,Cr、Ni、Cu、Zn、Cd和Pb的总浓度分别在25.8 - 68.5、12.1 - 36.7、3.25 - 48.74、33.5 - 472.4、0.16 - 0.69和9.04 - 90.74 mg·kg⁻¹范围内。沉积物中的重金属含量从水库上游到三门峡大坝明显增加。渭河下游沉积物中Ni、Cu、Zn、Cd、Pb的浓度高于上游。渭河是黄河最大的支流,典型污染支流(宏农涧河)沉积物中重金属明显积累,这可能归因于工业废水的长期排放。三门峡水库沉积物污染指数(SPI)在1.83至7.39之间,平均值为3.11。渭河入流后下游沉积物污染加剧,宏农涧河口SPI达到6.33,为中等风险。表层沉积物中Cd、Cu和Pb质量分数的可交换态和碳酸盐态分别占63.8% - 85.7%、6.58% - 22.62%和10.6% - 28.9%。支流污染物排放导致三门峡流域下游重金属积累、生态风险加剧。表层沉积物中释放风险顺序为Cd>Pb>Cu>Ni。本文研究结论为沉积物污染治理和原位修复提供了参考依据。

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