通过炔烃复分解反应和 Diels-Alder 反应作为关键步骤，采用面向多样性的方法合成冠芳烷。
Diversity oriented approach to crownophanes by enyne metathesis and Diels-Alder reaction as key steps.
机构信息
Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai-400 076, India.
出版信息
J Org Chem. 2012 Jul 20;77(14):6314-8. doi: 10.1021/jo300766f. Epub 2012 Jul 10.
PMID:22731677
Abstract
Various crownophanes are assembled starting with simple phenol derivatives such as catechol, resorcinol, and hydroquinone. Here, cross-enyne metathesis (CEM) and Diels-Alder (DA) reaction have been used as key steps. This strategy has embedded six diversity points.
摘要
各种冠芳烷都是从简单的酚类衍生物如儿茶酚、间苯二酚和对苯二酚开始组装的。在这里，交叉烯炔复分解（CEM）和 Diels-Alder（DA）反应被用作关键步骤。该策略嵌入了六个多样性点。
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