• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

钼和钨单芳氧基亚胺茂（MAP）配合物对 1,3-二烯的 Z 选择性交叉复分解反应。

Z-selective metathesis homocoupling of 1,3-dienes by molybdenum and tungsten monoaryloxide pyrrolide (MAP) complexes.

机构信息

Department of Chemistry 6-331, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

出版信息

J Am Chem Soc. 2012 Jul 18;134(28):11334-7. doi: 10.1021/ja303220j. Epub 2012 Jul 2.

DOI:10.1021/ja303220j
PMID:22734508
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3417118/
Abstract

Molybdenum or tungsten monoaryloxide pyrrolide (MAP) complexes that contain OHIPT as the aryloxide (hexaisopropylterphenoxide) are effective catalysts for homocoupling of simple (E)-1,3-dienes to give (E,Z,E)-trienes in high yield and with high Z selectivities. A vinylalkylidene MAP species was shown to have the expected syn structure in an X-ray study. MAP catalysts that contain OHMT (hexamethylterphenoxide) are relatively inefficient.

摘要

钼或钨单芳氧基亚基吡咯烷（MAP）配合物，其中芳氧基亚基（六异丙基邻苯二酚）为 OHIPT（六异丙基邻苯二酚），是高效的催化剂，可使简单的（E）-1,3-二烯高收率和高 Z 选择性地发生同偶联，生成（E,Z,E）-三烯。在 X 射线研究中，显示出具有预期顺式结构的乙烯基亚烷基 MAP 物种。含有 OHMT（六甲基邻苯二酚）的 MAP 催化剂效率相对较低。

相似文献

1
Z-selective metathesis homocoupling of 1,3-dienes by molybdenum and tungsten monoaryloxide pyrrolide (MAP) complexes.钼和钨单芳氧基亚胺茂（MAP）配合物对 1,3-二烯的 Z 选择性交叉复分解反应。
J Am Chem Soc. 2012 Jul 18;134(28):11334-7. doi: 10.1021/ja303220j. Epub 2012 Jul 2.
2
Synthesis and Evaluation of Molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for Z-Selective Cross-Metathesis of Cyclooctene and Z-1,2-Dichloroethylene.钼和钨单芳氧卤化物亚烷基配合物的合成与评价及其在环辛烯和 Z-1,2-二氯乙烯的 Z-选择性交叉复分解反应中的应用。
J Am Chem Soc. 2016 Dec 7;138(48):15774-15783. doi: 10.1021/jacs.6b10499. Epub 2016 Nov 22.
3
Correction to "Z-Selective Metathesis Homocoupling of 1,3-Dienes by Molybdenum and Tungsten Monoaryloxide Pyrrolide (MAP) Complexes".对“钼和钨单芳氧基吡咯化物（MAP）配合物催化1,3 - 二烯的Z - 选择性复分解自偶联反应”的修正
J Am Chem Soc. 2017 Nov 15;139(45):16430. doi: 10.1021/jacs.7b11214. Epub 2017 Nov 7.
4
Endo-selective enyne ring-closing metathesis promoted by stereogenic-at-W mono-pyrrolide complexes.手性-at-W 单吡咯烷配合物促进的端烯炔环封易位反应。
Org Lett. 2011 Feb 18;13(4):784-7. doi: 10.1021/ol1030525. Epub 2011 Jan 20.
5
Efficient and selective formation of macrocyclic disubstituted Z alkenes by ring-closing metathesis (RCM) reactions catalyzed by Mo- or W-based monoaryloxide pyrrolide (MAP) complexes: applications to total syntheses of epilachnene, yuzu lactone, ambrettolide, epothilone C, and nakadomarin A.通过钼或钨基单芳氧基吡咯烷（MAP）配合物催化的环 closing metathesis (RCM) 反应高效且选择性地形成大环二取代 Z 烯：在艾里香烯、柚子内酯、香豆素内酯、埃坡霉素 C 和纳卡多马林 A 的全合成中的应用。
Chemistry. 2013 Feb 18;19(8):2726-40. doi: 10.1002/chem.201204045. Epub 2013 Jan 23.
6
Inversion of configuration at the metal in diastereomeric imido alkylidene monoaryloxide monopyrrolide complexes of molybdenum.钼的非对映异构亚胺基亚烷基单芳氧基单吡咯化物配合物中金属构型的翻转。
J Am Chem Soc. 2009 Jan 14;131(1):58-9. doi: 10.1021/ja808308e.
7
Factors controlling selectivity in the ring-opening metathesis polymerization of 3-substituted cyclooctenes by monoaryloxide pyrrolide imido alkylidene (MAP) catalysts.单芳氧基吡咯亚胺烷基（MAP）催化剂控制3-取代环辛烯开环易位聚合反应选择性的因素。
J Org Chem. 2014 Dec 19;79(24):11940-8. doi: 10.1021/jo501732q. Epub 2014 Sep 10.
8
Molybdenum and tungsten imido alkylidene complexes as efficient olefin-metathesis catalysts.钼和钨亚胺基亚烷基配合物作为高效的烯烃复分解催化剂。
Angew Chem Int Ed Engl. 2003 Oct 6;42(38):4592-633. doi: 10.1002/anie.200300576.
9
Z-selective olefin metathesis processes catalyzed by a molybdenum hexaisopropylterphenoxide monopyrrolide complex.由六异丙基三联苯氧基钼单吡咯配合物催化的Z-选择性烯烃复分解反应过程
J Am Chem Soc. 2009 Jun 17;131(23):7962-3. doi: 10.1021/ja902738u.
10
Molybdenum chloride catalysts for Z-selective olefin metathesis reactions.用于Z选择性烯烃复分解反应的氯化钼催化剂。
Nature. 2017 Feb 2;542(7639):80-85. doi: 10.1038/nature21043. Epub 2017 Jan 23.

引用本文的文献

1
Degradation and Transformation Mechanisms of Alkylamides Exposed to UVB Light.暴露于中波紫外线（UVB）下的烷基酰胺的降解与转化机制
Foods. 2023 Dec 6;12(24):4392. doi: 10.3390/foods12244392.
2
Merging Grubbs second-generation catalyst with photocatalysis enables -selective metathesis of olefins: scope, limitations, and mechanism.将格拉布第二代催化剂与光催化相结合可实现烯烃的 - 选择性复分解反应：范围、局限性及机理。
Chem Sci. 2022 Sep 22;13(41):12065-12070. doi: 10.1039/d2sc03961c. eCollection 2022 Oct 26.
3
DFT Calculations of H NMR Chemical Shifts of Geometric Isomers of Conjugated Linolenic Acids, Hexadecatrienyl Pheromones, and Model Triene-Containing Compounds: Structures in Solution and Revision of NMR Assignments.DFT 计算共轭亚麻酸、十六碳三烯性信息素及其模型三烯化合物的几何异构体的 H NMR 化学位移：溶液中的结构和 NMR 分配的修订。
Molecules. 2021 Jun 7;26(11):3477. doi: 10.3390/molecules26113477.
4
Mechanism of Olefin Metathesis with Neutral and Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes.中性和阳离子钼亚胺基亚烷基氮杂环卡宾配合物的烯烃复分解反应机理
J Am Chem Soc. 2019 May 22;141(20):8264-8276. doi: 10.1021/jacs.9b02092. Epub 2019 May 9.
5
Synthesis of Linear (Z)-α,β-Unsaturated Esters by Catalytic Cross-Metathesis. The Influence of Acetonitrile.催化交叉复分解合成直链（Z）-α，β-不饱和酯。乙腈的影响。
Angew Chem Int Ed Engl. 2016 Oct 10;55(42):13210-13214. doi: 10.1002/anie.201608087.
6
Synthesis of Tungsten Imido Alkylidene Complexes that Contain an Electron-Withdrawing Imido Ligand.含吸电子亚胺配体的钨亚胺亚烷基配合物的合成。
Organometallics. 2014 Oct 13;33(19):5342-5348. doi: 10.1021/om5006676. Epub 2014 Sep 17.
7
Synthesis of Molybdenum and Tungsten Alkylidene Complexes That Contain Sterically Demanding Arenethiolate Ligands.含空间位阻较大的芳硫醇盐配体的钼和钨亚烷基配合物的合成。
Organometallics. 2014 Oct 13;33(19):5334-5341. doi: 10.1021/om500655n. Epub 2014 Sep 22.
8
Evolution of catalytic stereoselective olefin metathesis: from ancillary transformation to purveyor of stereochemical identity.催化立体选择性烯烃复分解反应的演变：从辅助转化到立体化学特性的提供者
J Org Chem. 2014 Jun 6;79(11):4763-92. doi: 10.1021/jo500467z. Epub 2014 Apr 10.
9
Investigations into Ruthenium Metathesis Catalysts with Six-Membered Chelating NHC Ligands: Relationship between Catalyst Structure and Stereoselectivity.含六元螯合NHC配体的钌复分解催化剂的研究：催化剂结构与立体选择性之间的关系
Organometallics. 2013 Sep 23;32(18). doi: 10.1021/om4006966.
10
Alkene chemoselectivity in ruthenium-catalyzed Z-selective olefin metathesis.钌催化 Z-选择性烯烃复分解反应中的烯烃化学选择性。
Angew Chem Int Ed Engl. 2013 Aug 19;52(34):9001-4. doi: 10.1002/anie.201302724. Epub 2013 Jul 5.

本文引用的文献

1
Enol ethers as substrates for efficient Z- and enantioselective ring-opening/cross-metathesis reactions promoted by stereogenic-at-Mo complexes: utility in chemical synthesis and mechanistic attributes.烯醇醚作为手性钼配合物促进的高效 Z 型和对映选择性开环/交叉复分解反应的底物：在化学合成中的应用和反应机理的特点。
J Am Chem Soc. 2012 Feb 8;134(5):2788-99. doi: 10.1021/ja210946z. Epub 2012 Jan 24.
2
Z-Selective olefin metathesis reactions promoted by tungsten oxo alkylidene complexes.钨氧亚烷基配合物促进的 Z-选择性烯烃复分解反应。
J Am Chem Soc. 2011 Dec 28;133(51):20754-7. doi: 10.1021/ja210349m. Epub 2011 Nov 30.
3
Synthesis of macrocyclic natural products by catalyst-controlled stereoselective ring-closing metathesis.通过催化剂控制的立体选择性环 closing metathesis 合成大环天然产物。
Nature. 2011 Nov 2;479(7371):88-93. doi: 10.1038/nature10563.
4
Isolation of pure disubstituted E olefins through Mo-catalyzed Z-selective ethenolysis of stereoisomeric mixtures.通过钼催化的立体异构混合物的 Z-选择性乙叉化反应分离纯二取代 E-烯烃。
J Am Chem Soc. 2011 Aug 3;133(30):11512-4. doi: 10.1021/ja205002v. Epub 2011 Jul 7.
5
Room Temperature Z-Selective Homocoupling of α Olefins by Tungsten Catalysts.钨催化剂催化α-烯烃在室温下的Z-选择性自偶联反应
Organometallics. 2011;30(7):1780-1782. doi: 10.1021/om200150c.
6
Z-Selective and Syndioselective Ring-Opening Metathesis Polymerization (ROMP) Initiated by MonoAryloxidePyrrolide (MAP) Catalysts.单芳氧基吡咯烷（MAP）催化剂引发的Z-选择性和间同立构选择性开环易位聚合（ROMP）
Macromolecules. 2010 Sep 28;43(18):7515-7522. doi: 10.1021/ma101375v.
7
Catalytic Z-selective olefin cross-metathesis for natural product synthesis.用于天然产物合成的催化 Z-选择性烯烃交叉复分解反应。
Nature. 2011 Mar 24;471(7339):461-6. doi: 10.1038/nature09957.
8
Endo-selective enyne ring-closing metathesis promoted by stereogenic-at-W mono-pyrrolide complexes.手性-at-W 单吡咯烷配合物促进的端烯炔环封易位反应。
Org Lett. 2011 Feb 18;13(4):784-7. doi: 10.1021/ol1030525. Epub 2011 Jan 20.
9
Highly Z-selective metathesis homocoupling of terminal olefins.高 Z 选择性末端烯烃复分解同系化反应。
J Am Chem Soc. 2009 Nov 25;131(46):16630-1. doi: 10.1021/ja908098t.
10
Endo-selective enyne ring-closing metathesis promoted by stereogenic-at-Mo monoalkoxide and monoaryloxide complexes. Efficient synthesis of cyclic dienes not accessible through reactions with Ru carbenes.由钼中心手性单醇盐和单芳氧基配合物促进的分子内选择性烯炔闭环复分解反应。高效合成通过与钌卡宾反应无法获得的环状二烯。
J Am Chem Soc. 2009 Aug 5;131(30):10652-61. doi: 10.1021/ja904098h.