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功能化金纳米粒子作为纳米传感器,通过表面增强拉曼散射实现对银离子和银纳米粒子的灵敏和选择性检测。

Functionalized gold nanoparticles as nanosensor for sensitive and selective detection of silver ions and silver nanoparticles by surface-enhanced Raman scattering.

机构信息

Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry and Environment, Beihang University, Beijing 100191, PR China.

出版信息

Analyst. 2012 Sep 7;137(17):3925-8. doi: 10.1039/c2an35670h. Epub 2012 Jun 29.

DOI:10.1039/c2an35670h
PMID:22745933
Abstract

We have developed a surface-enhanced Raman scattering (SERS) nanosensor firstly for Ag ions and Ag nanoparticles detection based on 2-mercaptoisonicotinic acid (2MNA)-functionalized Au nanoparticles. Ag(+) can coordinate with 2MNA resutling in a variation of its SERS spectrum, which is used as a criterion to determine Ag(+) in a solution. This sensor exhibits a detection limit no more than 25 nM and has a high selectivity against other metal ions. More importantly, it can be directly applied in real sample detection.

摘要

我们开发了一种基于 2-巯基异烟酸(2MNA)功能化的金纳米粒子的表面增强拉曼散射(SERS)纳米传感器,用于 Ag 离子和 Ag 纳米粒子的检测。Ag(+)可以与 2MNA 配位,导致其 SERS 光谱发生变化,可用于溶液中 Ag(+)的测定。该传感器的检测限不超过 25 nM,对其他金属离子具有很高的选择性。更重要的是,它可以直接应用于实际样品的检测。

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