Dipartimento Farmaco-chimico, Facoltà di Farmacia, Università degli Studi di Messina, viale Annunziata, 98168 Messina, Italy.
J Chromatogr A. 2012 Oct 26;1261:23-36. doi: 10.1016/j.chroma.2012.05.074. Epub 2012 Jun 15.
The present contribution is focused on the exploitation of the micro-bore (MB) open-tubular column (ID≤0.18 mm), in current-day gas chromatography. The vast majority of GC methods involve the use of MB columns, from a variety of one-dimensional techniques (conventional and high speed), to different forms of heart-cutting and comprehensive multidimensional methodologies. Various aspects related to the use of MB open-tubular capillaries will be described and critically discussed, along with a series of pertinent applications. A series of works from the past have also been cited, essentially because many approaches today-applied, derive from the ideas of the past. Obviously, the present contribution does not review the entire history of the micro-bore capillary (more than one book would be necessary); rather, it intends to portray the great contribution that such analytical tools provide in enhancing two fundamental GC features, namely separation power and speed.
本研究集中于微径（MB）开管柱（ID≤0.18mm）在现代气相色谱中的应用。目前绝大多数 GC 方法都涉及使用 MB 柱，从各种一维技术（常规和高速）到不同形式的分段切割和综合多维方法。本文将对使用 MB 开管毛细管的各个方面进行描述和批判性讨论，并结合一系列相关应用。本文还引用了过去的一系列工作，主要是因为当今应用的许多方法都源自过去的理念。显然，本研究并不是对微径毛细管的整个历史进行综述（这需要不止一本书）；相反，它旨在描绘这种分析工具在增强 GC 的两个基本特征（即分离能力和速度）方面的巨大贡献。
