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通过共焦成像和荧光相关光谱法监测聚合物共混物中相分离的动力学。

Monitoring the dynamics of phase separation in a polymer blend by confocal imaging and fluorescence correlation spectroscopy.

机构信息

Max-Planck-Institut für Polymerforschung, Mainz, Germany.

出版信息

Macromol Rapid Commun. 2012 Sep 26;33(18):1568-73. doi: 10.1002/marc.201200322. Epub 2012 Jul 3.

DOI:10.1002/marc.201200322
PMID:22761004
Abstract

The phase separation of the polymer blend polystyrene/poly(methyl phenyl siloxane) (PS/PMPS) is studied in situ by laser scanning confocal microscopy (LSCM) and by fluorescence correlation spectroscopy (FCS) at macroscopic and microscopic length scales, respectively. It is shown for the first time that FCS when combined with LSCM can provide independent information on the local concentration within the phase-separated domains as well as the interfacial width.

摘要

通过激光扫描共焦显微镜(LSCM)和荧光相关光谱(FCS)分别在宏观和微观尺度上原位研究了聚合物共混物聚苯乙烯/聚(甲基苯基硅氧烷)(PS/PMPS)的相分离。首次表明,将 FCS 与 LSCM 结合使用可以提供关于相分离域内局部浓度以及界面宽度的独立信息。

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