• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

工程塑料的新时代：可持续脂肪族聚对苯二甲酸乙二酯/聚2,5-呋喃二甲酸乙二酯共混物的相容性及前景

A New Era in Engineering Plastics: Compatibility and Perspectives of Sustainable Alipharomatic Poly(ethylene terephthalate)/Poly(ethylene 2,5-furandicarboxylate) Blends.

作者信息

Papageorgiou Dimitrios G, Tsetsou Irini, Ioannidis Raphael O, Nikolaidis George N, Exarhopoulos Stylianos, Kasmi Nejib, Bikiaris Dimitrios N, Achilias Dimitris S, Papageorgiou George Z

机构信息

School of Engineering and Materials Science, Queen Mary University of London, Mile End Road, London E1 4NS, UK.

Chemistry Department, University of Ioannina, P.O. Box 1186, 45110 Ioannina, Greece.

出版信息

Polymers (Basel). 2021 Mar 29;13(7):1070. doi: 10.3390/polym13071070.

DOI:10.3390/polym13071070
PMID:33805314
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8038036/
Abstract

The industrialisation of poly(ethylene 2,5-furandicarboxylate) for total replacement of poly(ethylene terephthalate) in the polyester market is under question. Preparation of high-performing polymer blends is a well-established strategy for tuning the properties of certain homopolymers and create tailor-made materials to meet the demands for a number of applications. In this work, the structure, thermal properties and the miscibility of a series of poly(ethylene terephthalate)/poly(ethylene 2,5-furandicarboxylate) (PET/PEF) blends have been studied. A number of thermal treatments were followed in order to examine the thermal transitions, their dynamic state and the miscibility characteristics for each blend composition. Based on their glass transition temperatures and melting behaviour the PET/PEF blends are miscible at high and low poly(ethylene terephthalate) (PET) contents, while partial miscibility was observed at intermediate compositions. The multiple melting was studied and their melting point depression was analysed with the Flory-Huggins theory. In an attempt to further improve miscibility, reactive blending was also investigated.

摘要

聚（2,5-呋喃二甲酸乙二酯）在聚酯市场中完全替代聚（对苯二甲酸乙二酯）的工业化进程受到质疑。制备高性能聚合物共混物是一种成熟的策略，用于调整某些均聚物的性能并制造定制材料以满足多种应用的需求。在这项工作中，研究了一系列聚（对苯二甲酸乙二酯）/聚（2,5-呋喃二甲酸乙二酯）（PET/PEF）共混物的结构、热性能和相容性。进行了多种热处理，以研究每种共混物组成的热转变、动态状态和相容性特征。基于它们的玻璃化转变温度和熔融行为，PET/PEF共混物在高和低聚（对苯二甲酸乙二酯）（PET）含量下是可混溶的，而在中间组成下观察到部分混溶。研究了多重熔融，并使用弗洛里-哈金斯理论分析了它们的熔点降低。为了进一步提高相容性，还研究了反应性共混。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/97ca76c4f09d/polymers-13-01070-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/279ccad52e19/polymers-13-01070-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/b31defbad754/polymers-13-01070-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/5f89eaa59d78/polymers-13-01070-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/4d9e57edc8c6/polymers-13-01070-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/cb7b666c7d6a/polymers-13-01070-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/c97cf601f303/polymers-13-01070-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/acf286adc282/polymers-13-01070-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/000c3b28b3f1/polymers-13-01070-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/0510faffe0a8/polymers-13-01070-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/e2cdbb484f2d/polymers-13-01070-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/f207a0b8ed68/polymers-13-01070-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/97ca76c4f09d/polymers-13-01070-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/279ccad52e19/polymers-13-01070-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/b31defbad754/polymers-13-01070-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/5f89eaa59d78/polymers-13-01070-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/4d9e57edc8c6/polymers-13-01070-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/cb7b666c7d6a/polymers-13-01070-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/c97cf601f303/polymers-13-01070-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/acf286adc282/polymers-13-01070-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/000c3b28b3f1/polymers-13-01070-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/0510faffe0a8/polymers-13-01070-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/e2cdbb484f2d/polymers-13-01070-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/f207a0b8ed68/polymers-13-01070-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2810/8038036/97ca76c4f09d/polymers-13-01070-g011.jpg

相似文献

1
A New Era in Engineering Plastics: Compatibility and Perspectives of Sustainable Alipharomatic Poly(ethylene terephthalate)/Poly(ethylene 2,5-furandicarboxylate) Blends.工程塑料的新时代：可持续脂肪族聚对苯二甲酸乙二酯/聚2,5-呋喃二甲酸乙二酯共混物的相容性及前景
Polymers (Basel). 2021 Mar 29;13(7):1070. doi: 10.3390/polym13071070.
2
Exploring Next-Generation Engineering Bioplastics: Poly(alkylene furanoate)/Poly(alkylene terephthalate) (PAF/PAT) Blends.探索下一代工程生物塑料：聚（亚烷基呋喃酸酯）/聚（亚烷基对苯二甲酸酯）（PAF/PAT）共混物
Polymers (Basel). 2019 Mar 23;11(3):556. doi: 10.3390/polym11030556.
3
Sustainable Plastics from Biomass: Blends of Polyesters Based on 2,5-Furandicarboxylic Acid.来自生物质的可持续塑料：基于2,5-呋喃二甲酸的聚酯共混物。
Polymers (Basel). 2020 Jan 16;12(1):225. doi: 10.3390/polym12010225.
4
Blend Miscibility of Poly(ethylene terephthalate) and Aromatic Polyesters from Salicylic Acid.由水杨酸衍生的芳香聚酯与聚对苯二甲酸乙二酯的共混相容性
J Phys Chem B. 2021 Jan 14;125(1):450-460. doi: 10.1021/acs.jpcb.0c09322. Epub 2021 Jan 5.
5
Biobased Engineering Thermoplastics: Poly(butylene 2,5-furandicarboxylate) Blends.生物基工程热塑性塑料：聚（2,5-呋喃二甲酸丁二醇酯）共混物
Polymers (Basel). 2019 May 29;11(6):937. doi: 10.3390/polym11060937.
6
Environmentally Friendly Polymer Blends Based on Post-Consumer Glycol-Modified Poly(Ethylene Terephthalate) (PET-G) Foils and Poly(Ethylene 2,5-Furanoate) (PEF): Preparation and Characterization.基于消费后二醇改性聚对苯二甲酸乙二酯（PET-G）薄片和聚2,5-呋喃二甲酸乙二酯（PEF）的环保聚合物共混物：制备与表征
Materials (Basel). 2020 Jun 12;13(12):2673. doi: 10.3390/ma13122673.
7
Synthesis of poly(ethylene furandicarboxylate) polyester using monomers derived from renewable resources: thermal behavior comparison with PET and PEN.使用源自可再生资源的单体合成聚（呋喃二甲酸乙二酯）聚酯：与聚对苯二甲酸乙二酯和聚萘二甲酸乙二酯的热行为比较
Phys Chem Chem Phys. 2014 May 7;16(17):7946-58. doi: 10.1039/c4cp00518j.
8
Glass transition dynamics and cooperativity length of poly(ethylene 2,5-furandicarboxylate) compared to poly(ethylene terephthalate).聚（2,5-呋喃二甲酸乙二酯）与聚对苯二甲酸乙二酯相比的玻璃化转变动力学和协同长度。
Phys Chem Chem Phys. 2016 Jun 22;18(25):16647-58. doi: 10.1039/c6cp01227b.
9
Prediction of the Miscibility of PBAT/PLA Blends.聚己二酸/对苯二甲酸丁二醇酯/聚乳酸共混物的混溶性预测
Polymers (Basel). 2021 Jul 16;13(14):2339. doi: 10.3390/polym13142339.
10
Improving the Wet-Spinning and Drawing Processes of Poly(lactide)/Poly(ethylene furanoate) and Polylactide/Poly(dodecamethylene furanoate) Fiber Blends.改善聚丙交酯/聚（乙烯基呋喃酸酯）和聚丙交酯/聚（十二亚甲基呋喃酸酯）纤维共混物的湿法纺丝和拉伸工艺
Polymers (Basel). 2022 Jul 17;14(14):2910. doi: 10.3390/polym14142910.

引用本文的文献

1
Ecofriendly PEF- and PBF-Based Blends with Epoxidized Natural Rubber: Unraveling the Structure-Property Relationship.基于环保脉冲电场处理和脉冲蓝光处理并与环氧化天然橡胶共混的材料：解析结构-性能关系
Materials (Basel). 2025 Aug 28;18(17):4040. doi: 10.3390/ma18174040.
2
Toughening Brittle Poly(ethylene Furanoate) with Linear Low-Density Polyethylene via Interface Modulation Using Reactive Compatibilizers.通过使用反应性增容剂进行界面调控，用线性低密度聚乙烯增韧脆性聚（呋喃二甲酸乙二酯）
ACS Omega. 2025 Feb 4;10(6):5756-5769. doi: 10.1021/acsomega.4c09301. eCollection 2025 Feb 18.
3
Graphene Nanoplatelets' Effect on the Crystallization, Glass Transition, and Nanomechanical Behavior of Poly(ethylene 2,5-furandicarboxylate) Nanocomposites.

本文引用的文献

1
Blend Miscibility of Poly(ethylene terephthalate) and Aromatic Polyesters from Salicylic Acid.由水杨酸衍生的芳香聚酯与聚对苯二甲酸乙二酯的共混相容性
J Phys Chem B. 2021 Jan 14;125(1):450-460. doi: 10.1021/acs.jpcb.0c09322. Epub 2021 Jan 5.
2
Theory of Formation of Polymer Crystals with Folded Chains in Dilute Solution.稀溶液中折叠链状聚合物晶体的形成理论
J Res Natl Bur Stand A Phys Chem. 1960 Jan-Feb;64A(1):73-102. doi: 10.6028/jres.064A.007. Epub 1960 Feb 1.
3
Bottle-grade polyethylene furanoate from ring-opening polymerisation of cyclic oligomers.
石墨烯纳米片对聚（2,5-呋喃二甲酸乙二酯）纳米复合材料的结晶、玻璃化转变及纳米力学行为的影响
Molecules. 2022 Oct 6;27(19):6653. doi: 10.3390/molecules27196653.
4
The Road to Bring FDCA and PEF to the Market.将FDCA和PEF推向市场之路。
Polymers (Basel). 2022 Feb 26;14(5):943. doi: 10.3390/polym14050943.
环状低聚物开环聚合制备瓶级呋喃聚酯
Nat Commun. 2018 Jul 24;9(1):2701. doi: 10.1038/s41467-018-05147-y.
4
Progress of Polymers from Renewable Resources: Furans, Vegetable Oils, and Polysaccharides.可再生资源聚合物的进展：呋喃、植物油和多糖
Chem Rev. 2016 Feb 10;116(3):1637-69. doi: 10.1021/acs.chemrev.5b00264. Epub 2015 Aug 20.
5
Synthetic Polymers from Sugar-Based Monomers.基于糖基单体的合成聚合物。
Chem Rev. 2016 Feb 10;116(3):1600-36. doi: 10.1021/acs.chemrev.5b00242. Epub 2015 Aug 20.
6
Synthesis of poly(ethylene furandicarboxylate) polyester using monomers derived from renewable resources: thermal behavior comparison with PET and PEN.使用源自可再生资源的单体合成聚（呋喃二甲酸乙二酯）聚酯：与聚对苯二甲酸乙二酯和聚萘二甲酸乙二酯的热行为比较
Phys Chem Chem Phys. 2014 May 7;16(17):7946-58. doi: 10.1039/c4cp00518j.
7
Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates.高效有机金属卤化物钙钛矿平面异质结太阳能电池在柔性聚合物衬底上。
Nat Commun. 2013;4:2761. doi: 10.1038/ncomms3761.
8
Monitoring the dynamics of phase separation in a polymer blend by confocal imaging and fluorescence correlation spectroscopy.通过共焦成像和荧光相关光谱法监测聚合物共混物中相分离的动力学。
Macromol Rapid Commun. 2012 Sep 26;33(18):1568-73. doi: 10.1002/marc.201200322. Epub 2012 Jul 3.
9
Tailoring impact toughness of poly(L-lactide)/poly(ε-caprolactone) (PLLA/PCL) blends by controlling crystallization of PLLA matrix.通过控制 PLLA 基体结晶来调整聚（L-丙交酯）/聚（ε-己内酯）（PLLA/PCL）共混物的冲击韧性。
ACS Appl Mater Interfaces. 2012 Feb;4(2):897-905. doi: 10.1021/am201564f. Epub 2012 Jan 20.