Stereoselective total synthesis of dodecagalacturonic acid, a phytoalexin elicitor of soybean.
作者信息
Nakahara Y, Ogawa T
机构信息
RIKEN (The Institute of Physical and Chemical Research), Saitama, Japan.
出版信息
Carbohydr Res. 1990 Sep 19;205:147-59. doi: 10.1016/0008-6215(90)80135-p.
PMID:2276132
Abstract
O-(alpha-D-Galactopyranosyluronic acid)-[(1----4)-O-(alpha-D-galactopyranosyluronic acid)]10-D-galactopyranuronic acid (1), an endogenous elicitor of the phytoalexin of soybean, was synthesized by way of highly stereoselective glycosylations that involved glycosyl fluorides as the donors and oxidation of the twelve primary hydroxyl groups in the alpha-(1----4)-linked galactododecaoside derivative.
摘要
Zotero 插件