Department of Chemistry, Birla Institute of Technology and Science (BITS), Pilani, Rajasthan 333 031, India.
Dalton Trans. 2012 Aug 21;41(31):9276-9. doi: 10.1039/c2dt30771e. Epub 2012 Jul 4.
Strong solid-state greenish-blue emitting, mono-cyclometalated iridium complexes, [Ir(ppy)(PPh(3))(2)(H)(Cl)], 2a and [Ir(F(2)ppy)(PPh(3))(2)(H)(Cl)], 2b [ppyH = 2-phenylpyridine; F(2)ppyH = 2-(2',4'-difluoro)phenylpyridine], have been synthesized by a convenient route. The 'aggregation induced enhanced phosphorescence (AIEP)' activity exhibited by these complexes has been rationalized.
强固态发绿蓝色荧光的单环金属铱配合物，[Ir(ppy)(PPh(3))(2)(H)(Cl)]，2a 和 [Ir(F(2)ppy)(PPh(3))(2)(H)(Cl)]，2b [ppyH = 2-苯基吡啶；F(2)ppyH = 2-(2',4'-二氟苯基)吡啶]，已经通过一种方便的路线合成。这些配合物表现出的“聚集诱导增强磷光(AIEP) ”活性已经得到了合理的解释。
