通过巯基-烯点击反应和开环聚合相结合合成的以环糊精为中心的星形聚合物。
Cyclodextrin-centred star polymers synthesized via a combination of thiol-ene click and ring opening polymerization.
机构信息
Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK.
出版信息
Chem Commun (Camb). 2012 Aug 21;48(65):8063-5. doi: 10.1039/c2cc33742h. Epub 2012 Jul 6.
PMID:22767077
Abstract
The synthesis of cyclodextrin-centred star polymers via thiol-ene addition of per-6-thio-β-cyclodextrin (CD-(SH)(7)) with vinyl terminated polymers is described. The obtained thiol-ene product was employed as an initiator for ring opening polymerization (ROP) of ε-caprolactone (ε-CL).
摘要
通过巯基-烯加成反应，将全-6-硫-β-环糊精（CD-（SH）（7））与末端带有乙烯基的聚合物反应，合成了以环糊精为中心的星型聚合物。所得的硫醇-烯产物可作为ε-己内酯（ε-CL）开环聚合（ROP）的引发剂。
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