基于简单水溶性 [FeFe]-氢化酶模型体系的光催化产氢。
Photocatalytic hydrogen production from a simple water-soluble [FeFe]-hydrogenase model system.
机构信息
Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry & Graduate University, The Chinese Academy of Sciences, Beijing 100190, PR China.
出版信息
Chem Commun (Camb). 2012 Aug 21;48(65):8081-3. doi: 10.1039/c2cc33097k. Epub 2012 Jul 6.
PMID:22772838
Abstract
Combined with a simple water soluble [FeFe]-hydrogenase mimic 1, Ru(bpy)(3)(2+) and ascorbic acid enable hydrogen production photocatalytically. More than 88 equivalents of H(2) were achieved in water, which is much better than that obtained in an organic solvent or a mixture of organic solvent and water.
摘要
结合一种简单的水溶性 [FeFe]-氢化酶模拟物 1，Ru(bpy)(3)(2+) 和抗坏血酸可以实现光催化制氢。在水中获得了超过 88 当量的 H(2)，这比在有机溶剂或有机溶剂和水的混合物中获得的要好得多。
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