碳-碳键形成：钯催化 N-对甲苯磺酰腙与烯丙醇的氧化交叉偶联。
Carbon-carbon bond formation: palladium-catalyzed oxidative cross-coupling of N-tosylhydrazones with allylic alcohols.
机构信息
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, PR China.
出版信息
Chemistry. 2012 Aug 20;18(34):10497-500. doi: 10.1002/chem.201200949. Epub 2012 Jul 10.
PMID:22782887
Abstract
In the zone: Pd-catalyzed oxidative cross-coupling of N-tosylhydrazones with allylic alcohols leads to CC bond formation. A palladium-carbene migratory insertion is proposed to play the key role in this transformation. The reaction proceeds with readily available starting materials to afford substituted alkenes in a highly stereoselective manner.
摘要
在区域内
Pd 催化的 N-对甲苯磺酰腙与烯丙醇的氧化交叉偶联导致 CC 键形成。提出钯-卡宾迁移插入在这种转化中起关键作用。该反应以易得的起始原料进行，以高立体选择性地提供取代的烯烃。
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