通过芳烃的 C-H 功能化实现芳基硫属元素化合物的高区域选择性合成。
Highly regioselective synthesis of aryl chalcogenides through C-H functionalization of arenes.
机构信息
Department of Chemistry, National Chung Hsing University, Taichung, 402, Taiwan, ROC.
出版信息
Chem Commun (Camb). 2012 Aug 28;48(67):8440-2. doi: 10.1039/c2cc33950a. Epub 2012 Jul 16.
PMID:22797474
Abstract
We report here the regioselective synthesis of aryl chalcogenides through the iridium-catalyzed meta C-H borylation followed by copper-catalyzed C-S coupling reaction with chalcogenide sources in one pot, giving the 3,5-disubstituted aryl chalcogenides with high regioselectivity and good yields.
摘要
我们在此报告了一种通过铱催化的间位 C-H 硼化反应，然后与硫属元素源进行铜催化的 C-S 偶联反应，一锅法合成芳基硫属化合物的区域选择性方法，以高产率高区域选择性得到 3,5-二取代芳基硫属化合物。
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