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2-[(1H-苯并咪唑-2-基)硫烷基]-1-苯基乙酮

2-[(1H-Benzimidazol-2-yl)sulfan-yl]-1-phenyl-ethanone.

作者信息

Abdel-Aziz Hatem A, Chia Tze Shyang, Fun Hoong-Kun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2262. doi: 10.1107/S1600536812028747. Epub 2012 Jun 30.

Abstract

The title compound, C(15)H(12)N(2)OS, adopts a twisted V-shape, with the S atom as the pivot. The benzimidazole ring system [maximum deviation = 0.015 (1) Å] makes a dihedral angle of 78.56 (7)° with the phenyl ring. The O atom of the ketone group is close to coplanar with its adjacent ring [O-C-C-C torsion angle = 11.0 (2)°]. In the crystal, mol-ecules are linked by N-H⋯N hydrogen bonds into an infinite chain along [001]. The crystal packing also features a C-H⋯π inter-action.

摘要

标题化合物C(15)H(12)N(2)OS呈扭曲的V形,以S原子为轴。苯并咪唑环系[最大偏差 = 0.015 (1) Å]与苯环形成78.56 (7)°的二面角。酮基的O原子与其相邻环接近共平面[O-C-C-C扭转角 = 11.0 (2)°]。在晶体中,分子通过N-H⋯N氢键沿[001]方向连接成无限链。晶体堆积还具有C-H⋯π相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5f06/3394045/a8848aa77df4/e-68-o2262-fig1.jpg

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