基于多足芳烃的通过正交超分子相互作用构建的聚合结构。
Pillar[5]arene-based polymeric architectures constructed by orthogonal supramolecular interactions.
机构信息
Key Laboratory of Mesoscopic Chemistry of MOE, Center for Multimolecular Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.
出版信息
Chem Commun (Camb). 2012 Sep 4;48(68):8529-31. doi: 10.1039/c2cc33943a. Epub 2012 Jul 17.
PMID:22801337
Abstract
Ureidopyrimidinone functionalized pillar[5]arene (UPyP5) was synthesized and employed to complex with a bisparaquat derivative (G) to form supramolecular polymers at relatively high concentration. The orthogonal binding interactions including quadruple hydrogen bonding and host-guest interaction should play vital roles in the construction of this linear assembly.
摘要
脲嘧啶并嘧啶酮功能化的[5]轮芳烃（UPyP5）被合成，并用于与双对醌衍生物（G）络合，在相对较高的浓度下形成超分子聚合物。包括四重氢键和主客体相互作用在内的正交结合相互作用，在这个线性组装体的构建中应该起着至关重要的作用。
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