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一种柱[5]芳烃稠合穴状配体:从正交自组装到超分子聚合物

A pillar[5]arene-fused cryptand: from orthogonal self-assembly to supramolecular polymer.

作者信息

Wang Qi, Cheng Ming, Zhao Yue, Wu Lin, Jiang Juli, Wang Leyong, Pan Yi

机构信息

Key Laboratory of Mesoscopic Chemistry of MOE, Center for Multimolecular Organic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.

出版信息

Chem Commun (Camb). 2015 Feb 28;51(17):3623-6. doi: 10.1039/c5cc00130g.

Abstract

A pillar[5]arene-fused cryptand with two different cavities was synthesized successfully. It was found that the novel tricyclic host could associate with two different guest species in an orthogonal manner. And based on this orthogonal self-assembly of two host-guest interactions, a novel type of supramolecular polymer was constructed easily and conveniently.

摘要

成功合成了一种具有两个不同空腔的柱[5]芳烃稠合穴醚。发现这种新型三环主体能够以正交方式与两种不同的客体物种缔合。基于这两种主客体相互作用的正交自组装,简便地构建了一种新型超分子聚合物。

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