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高氯酸铜（II）一水合物[1 -（吡啶-2 -基）乙酮肟][1 -（2 -吡啶-2 -基）乙酮肟]一水合物。

Aqua[1-(pyridin-2-yl)ethanone oximato][1-(2-pyridin-2-yl)ethanone oxime]-copper(II) perchlorate mono-hydrate.

作者信息

Zhong Baoyun, Li Shengli, Chen Guifang

机构信息

The Third Middle School in Liaocheng, Shandong 252059, People’s Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m874. doi: 10.1107/S1600536812023872. Epub 2012 Jun 13.

DOI:10.1107/S1600536812023872
PMID:22807722
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3393154/
Abstract

In the title compound, [Cu(C₇H₇N₂O)(C₇H₈N₂O)(H₂O)]ClO₄·H₂O, the Cu(II) ion is five-coordinated by the N atoms from the 1-(pyridin-2-yl)ethanone oximate and 1-(pyridin-2-yl)ethan-one oxime ligands and by the water O atom in a distorted square-pyramidal geometry. The two organic ligands are linked by an intra-molecular O-H⋯O hydrogen bond. In the crystal, mol-ecules and ions are linked by O-H⋯O hydrogen-bonding inter-actions, forming chains along the a axis. The perchlorate O atoms are disordered in a 0.58 (2):0.42 (2) ratio.

摘要

在标题化合物[Cu(C₇H₇N₂O)(C₇H₈N₂O)(H₂O)]ClO₄·H₂O中，Cu(II)离子由来自1-(吡啶-2-基)乙酮肟和1-(吡啶-2-基)乙酮肟配体的N原子以及水分子的O原子以扭曲的四方锥几何构型五配位。两个有机配体通过分子内O-H⋯O氢键相连。在晶体中，分子和离子通过O-H⋯O氢键相互作用相连，沿a轴形成链状结构。高氯酸根的O原子以0.58 (2):0.42 (2)的比例无序分布。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4619/3393154/7fa1c4358a9d/e-68-0m874-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4619/3393154/e8fe13113da9/e-68-0m874-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4619/3393154/7fa1c4358a9d/e-68-0m874-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4619/3393154/e8fe13113da9/e-68-0m874-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4619/3393154/7fa1c4358a9d/e-68-0m874-fig2.jpg

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本文引用的文献

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2
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A short history of SHELX.
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Evidence for single-chain magnet behavior in a Mn(III)-Ni(II) chain designed with high spin magnetic units: a route to high temperature metastable magnets.在由高自旋磁性单元设计的锰（III）-镍（II）链中发现单链磁体行为的证据：通往高温亚稳磁体的途径。
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