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双{N-[甲氧基(4-甲基苯甲酰胺基)甲基]-2,4-二甲基苯胺基-κ²N,O}铜(II)

Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ²N,O}copper(II).

作者信息

Yusof M Sukeri M, Kadir Maisara A, Yamin Bohari M

机构信息

Department of Chemical Sciences, Faculty of Science and Technology, Universiti Malaysia Terengganu, Mengabang Telipot, 21030 Kuala Terengganu, Terengganu, Malaysia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m894. doi: 10.1107/S1600536812025081. Epub 2012 Jun 13.

DOI:10.1107/S1600536812025081
PMID:22807736
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3393168/
Abstract

In the centrosymmetric mononuclear title complex, [Cu(C₁₈H₂₀N₂O₂)₂], the Cu(II) atom is four-coordinated in a trans-CuN₂O₂ square-planar geometry with the N-Cu-O chelate angle being 89.97 (11)°. The dihedral angles made by the planes defined by the aromatic ring carbons of the 4-methyl-benzene and 2,4-dimethyl-benzene fragments with the plane defined by the chelate ring are 13.43 (15) and 82.69 (13)° respectively. The angle between the planes defined by the aromatic carbons of the two rings is 89.40 (16)°. A a weak intra-molecular C-H⋯N hydrogen bond occurs.

摘要

在中心对称单核标题配合物[Cu(C₁₈H₂₀N₂O₂)₂]中，Cu(II)原子以反式-CuN₂O₂平面正方形几何构型进行四配位，N-Cu-O螯合角为89.97 (11)°。4-甲基苯和2,4-二甲基苯片段的芳环碳所定义的平面与螯合环所定义的平面形成的二面角分别为13.43 (15)°和82.69 (13)°。两个环的芳族碳所定义的平面之间的夹角为89.40 (16)°。存在一个弱的分子内C-H⋯N氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/44e1/3393168/18ce763b5715/e-68-0m894-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/44e1/3393168/18ce763b5715/e-68-0m894-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/44e1/3393168/18ce763b5715/e-68-0m894-fig1.jpg

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