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[1,1'-Dibenzyl-2,2'-(2-oxapropane-1,3-diyl)di(1H-benzimidazole)-κ³N³,O,N³']bis(2,4,6-trinitrophenolato-κO¹)manganese(II).

作者信息

Li Congfen, Kou Fan, Li Xinghan, Wu Hao, Wu Huilu

机构信息

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m923. doi: 10.1107/S1600536812026037. Epub 2012 Jun 16.

Abstract

In the title complex, [Mn(C₆H₂N₃O₇)₂(C₃₀H₂₆N₄O)], the Mn(II) atom is coordinated by the tridentate bis-benzimidazole ligand and two atoms of the picrate anions, in a distorted square-pyramidal geometry (τ = 0.038). One nitro O atom of one picrate ion is disordered over two sites with occupancies of 0.54 (5) and 0.46 (5).

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b50b/3393189/c23151631828/e-68-0m923-fig1.jpg

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