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链状聚[[[二水合-[3-(吡啶-4-基)苯甲酸根-κ(2)O,O']钆(III)]-双-[μ-3-(吡啶-4-基)苯甲酸根-κ(2)O:O']]一水合物]

catena-Poly[[[diaqua-[3-(pyridin-4-yl)benzoato-κ(2)O,O']gadolinium(III)]-bis-[μ-3-(pyridin-4-yl)benzoato-κ(2)O:O']] monohydrate].

作者信息

Li Dong-Ying, Li Guo-Ting

机构信息

Department of Environmental and Municipal Engineering, North China University of Water Conservancy and Electric Power, Zhengzhou 450011, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m928-9. doi: 10.1107/S1600536812026153. Epub 2012 Jun 16.

DOI:10.1107/S1600536812026153
PMID:22807760
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3393192/
Abstract

In the title coordination polymer, {[Gd(C(12)H(8)NO(2))(3)(H(2)O)(2)]·H(2)O}(n), the Gd(III) ion is ligated by one bidentate carboxyl-ate group, four monodentate bridging carboxyl-ate O atoms and two water mol-ecules. The resulting GdO(8) polyhedron approximates to a square anti-prism. The bridging ligands link the metal ions into a [100] chain, with each pair of adjacent metal ions being bridged by two ligands. Inter-chain O-H⋯O and O-H⋯N hydrogen bonds help to establish the packing.

摘要

在标题配位聚合物{[Gd(C₁₂H₈NO₂)₃(H₂O)₂]·H₂O}ₙ中，Gd(III)离子由一个双齿羧酸根基团、四个单齿桥连羧酸根O原子和两个水分子配位。所得的GdO₈多面体近似于一个方形反棱柱。桥连配体将金属离子连接成一条[100]链，每对相邻金属离子由两个配体桥连。链间的O—H⋯O和O—H⋯N氢键有助于形成堆积结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1be7/3393192/1555375e6dbe/e-68-0m928-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1be7/3393192/fd5612a6f84c/e-68-0m928-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1be7/3393192/1555375e6dbe/e-68-0m928-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1be7/3393192/fd5612a6f84c/e-68-0m928-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1be7/3393192/1555375e6dbe/e-68-0m928-fig2.jpg

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本文引用的文献

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Inorg Chem. 2010 Mar 15;49(6):2600-13. doi: 10.1021/ic901113p.
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A short history of SHELX.SHELX简史。
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