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双{1-[(1H-苯并三唑-1-基)甲基]-2-甲基-1H-咪唑-κN(3)}二氯合钴(II)

Bis{1-[(1H-benzotriazol-1-yl)meth-yl]-2-methyl-1H-imidazole-κN(3)}dichlorido-cobalt(II).

作者信息

Yang Haiyan, Li Yinghua, Zhao Yaomin, Li Wenzhuo, He Fang

机构信息

School of Materials and Chemical Engineering, Zhongyuan University of Technology, Zhengzhou 450007, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m948. doi: 10.1107/S1600536812026712. Epub 2012 Jun 20.

DOI:10.1107/S1600536812026712
PMID:22807773
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3393205/
Abstract

In the title mononuclear complex, [CoCl(2)(C(11)H(11)N(5))(2)], the Co(II) atom is four-coordinated by two ligand N atoms and two Cl atoms in a distorted tetra-hedral geometry. In the crystal, mol-ecules are stacked through π-π inter-actions [centroid-centroid distances = 3.473 (2), 3.807 (3), 3.883 (2) and 3.676 (2) Å], forming a three-dimensional supra-molecular network.

摘要

在标题单核配合物[CoCl₂(C₁₁H₁₁N₅)₂]中，Co(II)原子由两个配体N原子和两个Cl原子以扭曲的四面体几何构型进行四配位。在晶体中，分子通过π-π相互作用堆积[质心-质心距离 = 3.473 (2)、3.807 (3)、3.883 (2)和3.676 (2) Å]，形成三维超分子网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cd7/3393205/5cbf2c015443/e-68-0m948-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cd7/3393205/015d3facd3f3/e-68-0m948-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cd7/3393205/5cbf2c015443/e-68-0m948-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cd7/3393205/015d3facd3f3/e-68-0m948-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cd7/3393205/5cbf2c015443/e-68-0m948-fig2.jpg

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本文引用的文献

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Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m162. doi: 10.1107/S160053681200147X. Epub 2012 Jan 18.
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3D coordination framework with uncommon two-fold interpenetrated {3(3)5(9)6(3)}-lcy net and coordinated anion exchange.具有罕见的双折互穿{3(3)5(9)6(3)}-lcy网络和配位阴离子交换的3D配位框架
Chemistry. 2009;15(16):4049-56. doi: 10.1002/chem.200802515.
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A short history of SHELX.
SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.