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（联吡啶-κ(2)N,N'）氯代[N-(2-羟乙基)-N-异丙基-二硫代氨基甲酸盐-κ(2)S,S']锌(II)

(Bipyridine-κ(2)N,N')chlorido[N-(2-hydroxy-ethyl)-N-isopropyl-dithio-carbamato-κ(2)S,S']zinc(II).

作者信息

Mohamad Fatin Allia, Baba Ibrahim, Mohamed Tahir Mohamed Ibrahim, Tiekink Edward R T

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m958-9. doi: 10.1107/S1600536812027626. Epub 2012 Jun 23.

DOI:10.1107/S1600536812027626
PMID:22807780
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3393212/
Abstract

The Zn(II) atom in the title compound, [Zn(C(6)H(12)NOS(2))Cl(C(10)H(8)N(2))], is coordinated by a chelating N-2-hy-droxy-ethyl-N-isopropyl-dithio-carbamate ligand, a 2,2'-bipyridine ligand and a Cl atom. The resulting ClN(2)S(2) donor set defines a distorted square-pyramidal coordination geometry. Helical supra-molecular chains sustained by O-H⋯S hydrogen bonds and propagating along the b axis feature in the crystal packing. A three-dimensional architecture is stabilized by C-H⋯O, C-H⋯S and C-H⋯Cl inter-actions.

摘要

在标题化合物[Zn(C₆H₁₂NOS₂)Cl(C₁₀H₈N₂)]中，Zn(II)原子由一个螯合的N - 2 - 羟乙基 - N - 异丙基二硫代氨基甲酸盐配体、一个2,2'-联吡啶配体和一个Cl原子配位。由此形成的ClN₂S₂供体集定义了一种扭曲的四方锥配位几何构型。由O - H⋯S氢键维系并沿b轴延伸的螺旋超分子链是晶体堆积的特征。三维结构通过C - H⋯O、C - H⋯S和C - H⋯Cl相互作用得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bad/3393212/61b17d063ba8/e-68-0m958-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bad/3393212/c2cdb961df0e/e-68-0m958-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bad/3393212/1f9db1516440/e-68-0m958-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bad/3393212/61b17d063ba8/e-68-0m958-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bad/3393212/c2cdb961df0e/e-68-0m958-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bad/3393212/1f9db1516440/e-68-0m958-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bad/3393212/61b17d063ba8/e-68-0m958-fig3.jpg

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