二溴化[甲基 2-(喹啉-8-基氧基-κ(2)N,O)乙酸-κO]汞(II)
Dibromido[methyl 2-(quinolin-8-yl-oxy-κ(2)N,O)acetic acid-κO]mercury(II).
作者信息
Song Rui-Feng, Zhu Xue-Hua, Wang Yu-Hong
机构信息
School of Chemistry and Bioengineering, Suzhou University of Science and Technology, Suzhou 215009, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m968. doi: 10.1107/S1600536812028085. Epub 2012 Jun 23.
In the title complex, [HgBr(2)(C(12)H(11)NO(3))], the Hg(II) ion has a distorted core trigonal-planar geometry comprising two Br atoms and one quinoline N atom of the methyl 2-(quinolin-8-yl-oxy)acetic acid ligand. The angles around the Hg atom vary from 100.31 (15) to 152.65 (4)°. Two additional Hg⋯O inter-actions [2.739 (1) and 2.905 (1) Å] complete the coordination sphere about the Hg(II) atom.
在标题配合物[HgBr₂(C₁₂H₁₁NO₃)]中，Hg(II)离子具有扭曲的核心三角平面几何构型，由两个Br原子和2-(喹啉-8-基氧基)乙酸甲酯配体的一个喹啉N原子组成。Hg原子周围的角度在100.31 (15)°至152.65 (4)°之间变化。另外两个Hg⋯O相互作用[2.739 (1)和2.905 (1) Å]完善了Hg(II)原子周围的配位球。
Zotero 插件