Dibromido(dimethyl sulfoxide-κO)(6-methyl-2,2'-bipyridine-κ(2)N,N')cadmium.
作者信息
Shirvan Sadif A, Haydari Dezfuli Sara
机构信息
Department of Chemistry, Islamic Azad University, Omidieh Branch, Omidieh, Iran.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1124. doi: 10.1107/S1600536812033168. Epub 2012 Jul 28.
Abstract
In the title compound, [CdBr(2)(C(11)H(10)N(2))(C(2)H(6)OS)], the Cd(II) atom is five-coordinated in a distorted trigonal-bipyramidal geometry by two N atoms from a 6-methyl-2,2'-bipyridine ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. An intra-molecular C-H⋯O hydrogen bond occurs. The crystal structure is stabilized by C-H⋯Br hydrogen bonds and π-π contacts between the pyridine rings [centroid-centroid distances = 3.582 (5) and 3.582 (5) Å].
摘要
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