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9-[(2-甲氧基-苄基)氨基]-5-(3,4,5-三甲氧基-苯基)-5,5a,8a,9-四氢-呋喃并[3',4':6,7]萘并[2,3-d][1,3]二氧杂环戊烯-6(8H)-酮

9-[(2-Meth-oxy-benz-yl)amino]-5-(3,4,5-trimeth-oxy-phen-yl)-5,5a,8a,9-tetra-hydro-furo[3',4':6,7]naphtho-[2,3-d][1,3]dioxol-6(8H)-one.

作者信息

Shi Shaoyu, Tian Danli, Luo Gang, Ai Ting, Chen Hong

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2045. doi: 10.1107/S160053681202572X. Epub 2012 Jun 13.

DOI:10.1107/S160053681202572X
PMID:22807870
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3393313/
Abstract

In the title compound, C(30)H(31)NO(8), the tetra-hydro-furan ring and the six-membered ring fused to it both display envelope conformations, both having the same C atom as the flap. The dihedral angles between the benzene ring of the benzo[d][1,3]dioxole ring system and the other two benzene rings are 53.73 (3) and 83.30 (2)°. An intra-molecular N-H⋯O hydrogen bond is present. In the crystal, weak inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into chains parallel to the c axis.

摘要

在标题化合物C(30)H(31)NO(8)中，四氢呋喃环及其稠合的六元环均呈现信封式构象，二者的瓣均为同一个碳原子。苯并[d][1,3]二氧杂环戊烯环系的苯环与另外两个苯环之间的二面角分别为53.73 (3)°和83.30 (2)°。存在分子内N-H⋯O氢键。在晶体中，弱的分子间C-H⋯O氢键将分子连接成平行于c轴的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c722/3393313/10db769f4f5a/e-68-o2045-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c722/3393313/10db769f4f5a/e-68-o2045-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c722/3393313/10db769f4f5a/e-68-o2045-fig1.jpg

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本文引用的文献

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9-[(Furan-2-ylmeth-yl)amino]-5-(3,4,5-trimeth-oxy-phen-yl)-5,5a,8a,9-tetra-hydro-furo[3',4':6,7]naphtho-[2,3-d][1,3]dioxol-6(8H)-one.9-[(呋喃-2-基甲基)氨基]-5-(3,4,5-三甲氧基苯基)-5,5a,8a,9-四氢呋喃并[3',4':6,7]萘并[2,3-d][1,3]二氧杂环戊烯-6(8H)-酮
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