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[玛丽·居里——在她第二次获得诺贝尔奖百年之际谈她的化学成就]

[Maria Skłodowska-Curie--her chemistry at the centenary of the second Nobel Prize].

作者信息

Zagórski Zbigniew Paweł, Kornacka Ewa Maria

机构信息

Centrum Badań i Technologii Radiacyjnych, Instytut Chemii i Techniki Jadrowej w Warszawie.

出版信息

Kwart Hist Nauki Tech. 2012;57(1):39-70.

Abstract

The article presents from the perspective of one hundred years the work of Maria Curie-Skłodowska, which in many cases was ahead of the state of knowledge of the time. It opened new horizons and for this reason we made many digressions. The fact of awarding her the Nobel Prize twice is a sensation enough to present the values of careful activity of the Nobel Prize Committee that emphasizes the importance of Maria's achievements. A significant element of Maria Skłodowska-Curie's achievements was still mysterious character of the radiation in her time, and only chemical approach made it possible to organise the phenomena and explain the origin of the radiation. The essence of the research was an arduous separation of components following the track of growing radiation of successive fractions of preparations. This research was a start of the technology of educement of dispersed elements in great mass of materials. We underline the paramount role of the chemical research Maria Skłodowska conducted while still in Warsaw in the laboratories of the Museum of Industry and Agriculture under the guidance of an excellent chemist Józef Jerzy Boguski. Her research in Paris was the origin of the semi-commercial scale in chemistry and setting aside a special shed outside the university building was the beginning of the institutes that now function beyond universities and are key element of scientific and technical progress. Technology of splitting developed by Maria Skłodowska-Curie was applied also by other radiochemists, e.g. By Otto Hahn. Lively movement in radiochemistry of her lifetime resulted in Maria's disputes with e.g. German chemist Marckwald, who questioned the originality of polonium. The scientific disputes like this one Maria won triumphantly although in several others she had to accept opponents' argument, as in the case of radon. Her experiments were planned with utmost rationality as it was with the rejection of the hypothesis saying that radioactivity was transferred from the outer space or from the sun. A great part of Maria Skłodowska-Curie's work was connected with biology which was demonstrated by describing in mathematical terms, for the first time in the history of radiobiology, nonexistent at that time, of the phenomenon of inactivation of bacteria by ionizing radiation. We emphasize difficult conditions for the health of the radiochemists of the time but we don't find any proof that there was any influence of ionizing radiation on Maria's health. She must have absorbed much greater doses of radiation during her heroic work in the mobile radiological surgery at the front of the 1st World War. We don't think it's appropriate to speculate rashly about contamination with alpha emitters. Unfortunately, due to her family's protest it was impossible to collect samples of remains before their relocation to the Pantheon in Paris.

摘要

本文从百年视角展现了玛丽亚·居里-斯克洛多夫斯卡的工作,在很多情况下,她的工作领先于当时的知识水平。它开拓了新视野,因此我们进行了诸多旁征博引。她两次获得诺贝尔奖这一事实足以令人关注诺贝尔奖委员会审慎颁奖所秉持的价值观,该委员会强调了玛丽亚成就的重要性。玛丽亚·斯克洛多夫斯卡-居里成就中的一个重要因素是,在她那个时代,辐射的特性仍很神秘,只有通过化学方法才有可能梳理这些现象并解释辐射的来源。研究的核心是沿着制剂连续馏分辐射增强的轨迹艰难地分离成分。这项研究开启了从大量材料中提取分散元素的技术。我们着重指出玛丽亚·斯克洛多夫斯卡仍在华沙时,在工业与农业博物馆实验室,在杰出化学家约瑟夫·耶日·博古斯基的指导下所进行的化学研究的至关重要的作用。她在巴黎的研究开创了化学领域的半商业规模,在大学校舍外专门划出一个棚屋是如今独立于大学之外且成为科技进步关键要素的研究所的开端。玛丽亚·斯克洛多夫斯卡-居里所研发的分离技术也被其他放射化学家所应用,比如奥托·哈恩。在她有生之年放射化学领域的活跃发展导致玛丽亚与他人产生了诸多争论,例如与质疑钋的原创性的德国化学家马克瓦尔德。像这样的科学争论,玛丽亚虽大多取得了胜利,但在其他一些争论中她不得不接受对手的观点,比如在关于氡的争论中。她的实验规划极其合理,比如她摒弃了放射性是从外层空间或太阳转移而来的假说。玛丽亚·斯克洛多夫斯卡-居里的很大一部分工作与生物学相关,这一点体现在她首次以数学方式描述了当时放射生物学史上不存在的电离辐射使细菌失活的现象。我们强调了那个时代放射化学家面临的艰难健康状况,但并未找到任何证据表明电离辐射对玛丽亚的健康产生了影响。在第一次世界大战前线的移动放射外科手术中,她英勇工作期间肯定吸收了大得多的辐射剂量。我们认为贸然猜测她是否受到α发射体的污染并不合适。不幸的是,由于她家人的反对,在遗体迁往巴黎先贤祠之前无法采集样本。

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